1375931-46-6

Basic information

• Product Name: 2,6-dibromophenyl dimethylcarbamate
• Synonyms: 2,6-dibromophenyl dimethylcarbamate
• CAS NO: 1375931-46-6
• Molecular Weight: 322.984
• Mol File: 1375931-46-6.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2,6-dibromophenyl dimethylcarbamate(CAS DataBase Reference)
• NIST Chemistry Reference: 2,6-dibromophenyl dimethylcarbamate(1375931-46-6)
• EPA Substance Registry System: 2,6-dibromophenyl dimethylcarbamate(1375931-46-6)

Safety Data

• Hazardous Substances Data: 1375931-46-6(Hazardous Substances Data)

Upstream product

• 95-56-7 2-hydroxybromobenzene 
• 7305-04-6 o-bromophenyl N,N-dimethylcarbamate 
• 6969-90-0 phenyl N,N-dimethylcarbamate 

Downstream Products

• 608-33-3 2,6-dibromophenol 

Relevant articles and documents

Rhodium-Catalyzed ortho-Bromination of O-Phenyl Carbamates Accelerated by a Secondary Amide-Pendant Cyclopentadienyl Ligand

It has been established that a newly developed cyclopentadienyl rhodium(III) [CpARhIII] complex, bearing an acidic secondary amide moiety on the Cp ring, is able to catalyze the ortho-bromination of O-phenyl carbamates with N-bromosuccinimide (NBS) at room temperature. The presence of the acidic secondary amide moiety on the CpA ligand accelerates the bromination by the hydrogen bond between the acidic NH group of the CpA ligand and the carbonyl group of NBS.

High-yielding, versatile, and practical [Rh(III)Cp*]-catalyzed ortho bromination and iodination of arenes

We report a uniquely high-yielding, general, and practical ortho bromination and iodination reaction of different classes of aromatic compounds. This reaction occurs by Rh(III)-catalyzed C-H bond activation methodology and is therefore the first example of the application of this cationic catalyst for C-Br and C-I bond formation.