138380-27-5

Basic information

• Product Name: (1-ethoxyethenyl)methyl(naphth-1-yl)phenylsilane
• Synonyms: (1-ethoxyethenyl)methyl(naphth-1-yl)phenylsilane
• CAS NO: 138380-27-5
• Molecular Weight: 318.491
• Mol File: 138380-27-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (1-ethoxyethenyl)methyl(naphth-1-yl)phenylsilane(CAS DataBase Reference)
• NIST Chemistry Reference: (1-ethoxyethenyl)methyl(naphth-1-yl)phenylsilane(138380-27-5)
• EPA Substance Registry System: (1-ethoxyethenyl)methyl(naphth-1-yl)phenylsilane(138380-27-5)

Safety Data

• Hazardous Substances Data: 138380-27-5(Hazardous Substances Data)

Upstream product

• 960-82-7 rac-methyl(1-naphthyl)phenylchlorosilane 
• 109-92-2 ethyl vinyl ether 

Downstream Products

• 138380-34-4 1-(Methyl-naphthalen-1-yl-phenyl-silanyl)-ethanol 
• 16507-88-3 <α-Hydroxy-α-methyl-benzyl>-methyl-<1>naphthyl-phenyl-silan 
• 138457-71-3 methyl ketone 

Relevant articles and documents

Chiral Acylsilanes in Organic Synthesis. Diastereoselective 1,2 Additions to Racemic Alkoxymethyl-Substituted Acylsilanes

The synthesis of the three alkoxymethyl-sustituted acylsilanes 1-3 is described (Schemes 1 and 2).Their reactions with NaBH4 as well as PhLi gave the corresponding alcohols with moderate to good diastereoisomeric induction (up to 78percent de; see Table), depending upon the solvent used (Scheme 3).The results indicate that in Et2O, the reactions with PhLi proceed via 6-membered chelates (see C in Scheme 4) leading to the products with high de's (74 - 78percent).In THF, these chelates are not formed, and as a consequence, the additions take place with reversed and lower stereoselectivities (34 - 50percent de).