13883-39-1

Basic information

• Product Name: 3-BROMOPROPYLTRICHLOROSILANE
• Synonyms: 3-BROMOPROPYLTRICHLOROSILANE;(3-bromopropyl)trichloro-silan;3-(Trichlorosilyl)propyl bromide
• CAS NO: 13883-39-1
• Molecular Formula: C₃H₆BrCl₃Si
• Molecular Weight: 256.43
• EINECS: 237-650-1
• Product Categories: Protecting and Derivatizing Reagents;Self Assembly&Contact Printing;Self-Assembly Materials;SilanesProtection and Derivatization;Silicon-Based
• Mol File: 13883-39-1.mol
• Article Data: 5

Chemical Properties

• Boiling Point: 202-204 °C(lit.)
• Flash Point: 169 °F
• Appearance: /
• Density: 1.605 g/mL at 25 °C(lit.)
• Vapor Pressure: 0.563mmHg at 25°C
• Refractive Index: n20/D 1.494(lit.)
• BRN: 1737852
• CAS DataBase Reference: 3-BROMOPROPYLTRICHLOROSILANE(CAS DataBase Reference)
• NIST Chemistry Reference: 3-BROMOPROPYLTRICHLOROSILANE(13883-39-1)
• EPA Substance Registry System: 3-BROMOPROPYLTRICHLOROSILANE(13883-39-1)

Safety Data

• Hazard Codes: C
• Statements: 14-29-34
• Safety Statements: 26-36/37/39-45-28
• RIDADR: UN 2987 8/PG 2
• WGK Germany: 3
• F: 10-21
• TSCA: Yes
• Hazardous Substances Data: 13883-39-1(Hazardous Substances Data)

Usage

Description

3-BROMOPROPYLTRICHLOROSILANE is an organosilicon compound with the chemical formula C3H5BrCl3Si. It is a colorless to pale yellow liquid at room temperature and is known for its reactivity and versatility in chemical synthesis.

Uses

Used in Chemical Synthesis:
3-BROMOPROPYLTRICHLOROSILANE is used as a coupling agent for the preparation of self-assembled nonlinear optically (NLO) active chromophoric multilayers. It plays a crucial role in the formation of these multilayers, which have potential applications in various optical and electronic devices.
Used in Surface Modification:
3-BROMOPROPYLTRICHLOROSILANE is used as a reagent for the surface modification of silica nanofiber films and silica particles. This modification enhances the properties of these materials, such as their stability, reactivity, and compatibility with other substances, making them suitable for a wide range of applications in various industries.
Used in Nanotechnology:
In the field of nanotechnology, 3-BROMOPROPYLTRICHLOROSILANE is used as a key component in the synthesis of silica-based nanoparticles. These nanoparticles have potential applications in drug delivery, catalysis, and the development of advanced materials with unique properties.
Used in Coatings and Adhesives:
3-BROMOPROPYLTRICHLOROSILANE is also used in the formulation of coatings and adhesives, where its reactivity and compatibility with various substrates contribute to the development of high-performance products with improved adhesion, durability, and resistance to environmental factors.
Used in Electronics:
In the electronics industry, 3-BROMOPROPYLTRICHLOROSILANE is employed in the fabrication of semiconductor devices and components. Its ability to form stable bonds with silicon and other materials makes it a valuable component in the production of advanced electronic devices with enhanced performance and reliability.

InChI:InChI=1/C3H6BrCl3Si/c4-2-1-3-8(5,6)7/h1-3H2

Upstream product

• 106-95-6 allyl bromide 
• 107-37-9 allyltrichlorosilane 

Downstream Products

• 51826-90-5 1-bromo-3-trimethoxysilylpropane 
• 2351-33-9 1,1-dichlorosilacyclobutane 
• 10545-34-3 3-(trimethylsilyl)propyl bromide 
• 78957-27-4 6-bromo-3,3-dimethyl-3-sila-5-hexene 

Relevant articles and documents

Divergent synthesis of carbosilane wedges as dendritic building blocks: A new strategy towards core functionalised carbosilane dendrimers

A divergent route for the synthesis of carbosilane wedges containing either a bromine or amine as a focal point has been developed for the construction of core functionalised dendrimers; carbosilane dendrimers up to the third generation containing a 1,3,5-benzene triamide core capable of binding guest molecules via hydrogen bonding have been prepared.

Packing for use in resolution

The packing for use in resolution proposed for the liquid chromatography for particularly the opti-cal resolution of racemic compounds is prepared by reacting a silica gel carrier with a so-called silane treating agent to introduce a spacer part therein and chemically bonding it with a copper salt of a carboxylic or thiocarboxylic acid selected from the group consisting of optically active D- and L-2--acetizinecaroxylic acid, proline, hydroxyproline and allohydroxyproline. The steric bulkiness, the distance between the silica gel and the optically active group and the degree of hydrophobicity are specified so as to obtain an excellent resolving power.

SILAETHENE I. DARSTELLUNG UND CHARAKTERISIERUNG VON MONOSILACYCLOBUTANEN

Monosilacyclobutanes of the type RR' are prepared by ring closure reactions of 3-halopropylhalosilanes and by substitution of SiCl containing silacyclobutane rings with organometallic reagents (RMgX, LiR, NaCp).Under optimal experimental conditions yields between 50 and 95percent can be obtained by both procedures.Characterization of the compounds is accomplished by analytical (C, H, N) and NMR, IR and mass spectroscopic investigations.