139031-06-4

Basic information

• Product Name: Phosphine, bis(2,4,6-trimethylbenzoyl)-
• CAS NO: 139031-06-4
• Molecular Formula: C20H23O2P
• Molecular Weight: 326.375
• Mol File: 139031-06-4.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Phosphine, bis(2,4,6-trimethylbenzoyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Phosphine, bis(2,4,6-trimethylbenzoyl)-(139031-06-4)
• EPA Substance Registry System: Phosphine, bis(2,4,6-trimethylbenzoyl)-(139031-06-4)

Safety Data

• Hazardous Substances Data: 139031-06-4(Hazardous Substances Data)

Upstream product

• 109-63-7 boron trifluoride diethyl etherate 
• 7803-51-2 phosphan 
• 938-18-1 mesitylene-2-carboxylic acid chloride 
• 1253120-30-7 sodium bis(2,4,6-trimethylbenzoyl)phosphanide 

Downstream Products

• 1591652-81-1 di-(2-(bis(2,4,6-trimethylbenzoyl)phosphoryl)ethyl)sulfone 
• 1591653-12-1 2-(2-(bis(2,4,6-trimethylbenzoyl)phosphoryl)ethyl)pyridine 
• 1591652-65-1 3-((bis(2,4,6-trimethylbenzoyl)phosphoryl)methyl)dihydrofuran-2,5-dione 
• 1591653-32-5 3-(bis(2,4,6-trimethylbenzoyl)phosphoryl)propanoic acid 2-(2-ethoxyethoxy)ethyl ester 
• 1591652-66-2 2-((bis(2,4,6-trimethylbenzoyl)phosphoryl)methyl)succinic acid 
• 1591652-64-0 3-((bis(2,4,6-trimethylbenzoyl)phosphino)methyl)dihydrofuran-2,5-dione 
• 1591652-94-6 3-(trimethoxysilyl)propyl 3-(bis(2,4,6-trimethylbenzoyl)phosphino)propanoate 
• 1591652-90-2 methyl 3-(bis(2,4,6-trimethylbenzoyl)phosphino)propanoate 
• 1591653-06-3 N,N-methylene(bis(bis(2,4,6-trimethylbenzoyl)phosphino)propanamide) 
• 1591653-11-0 2-(2-(bis(2,4,6-trimethylbenzoyl)phosphino)ethyl)pyridine 
• 1591652-80-0 di(2-(bis(2,4,6-trimethylbenzoyl)phosphino)ethyl)sulfone 
• 1591653-39-2 trimethylolpropane tris[3-(bis(2,4,6-trimethylbenzoyl)phosphoryl)propanoate] 
• 1591653-41-6 trimethylolpropane monoacrylate-bis[3-(bis(2,4,6-trimethylbenzoyl)phosphoryl)propanoatel] 
• 1591653-43-8 trimethylolpropane bisacrylate-mono[3-(bis(2,4,6-trimethylbenzoyl)phosphoryl)propanoate] 

Relevant articles and documents

A VERSATILE PROCESS FOR THE PREPARATION OF ACYLPHOSPHINES

The present invention relates to a versatile, highly efficient process for the preparation of acylphosphines such as mono- and bisacylphosphines via reaction of phosphines (PH3 and higher homologues) or silylated phosphines with acylhalides in the presence of at least one lewis acid. The invention further relates to novel acyl phosphines obtainable by said process.

DERIVATIVES OF BISACYLPHOSPHINIC ACID, THEIR PREPARATION AND USE AS PHOTOINITIATORS

Bisacylphosphine oxide or bisacylphosphine sulfide compounds of formula (I) or (II) wherein R1, R2, R3, R1a, R2a and R3a independently of each other are C1-C4alkyl, C1-C4alkoxy or halogen; X is O, NR5 or S; or, if R4 is CI, F or Br, X is a direct bond; Y is O or S; n is 1 or 2; R4, if n is 1, for example is hydrogen, (CO)R6, (CO)OR6, (CO)NR5R6, (SO2)-R6, C1-C28alkyl, R4, if n = 2, is for example C1-C18alkylene; R5 is for example hydrogen, or C1-C12alkyl; R6 is for example C1-C12alkyl; R7, R8 and R9 independently of each other for example are C1-C4alkyl; R10 is for example C2-C18alkylene; X1 is O or S; m is 1, 2 or 3; Q represents one or two inorganic or organic cations with a charge of m+; are suitable photoinitiators, available by a claimed process.