1400743-02-3

Basic information

• Product Name: C₂₁H₃₁BO₃
• Synonyms: C₂₁H₃₁BO₃
• CAS NO: 1400743-02-3
• Molecular Weight: 342.286
• Mol File: 1400743-02-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₂₁H₃₁BO₃(CAS DataBase Reference)
• NIST Chemistry Reference: C₂₁H₃₁BO₃(1400743-02-3)
• EPA Substance Registry System: C₂₁H₃₁BO₃(1400743-02-3)

Safety Data

• Hazardous Substances Data: 1400743-02-3(Hazardous Substances Data)

Upstream product

• 246139-77-5 2-bromo-4-(tert-butyl)benzaldehyde 
• 61024-94-0 2-bromo-4-tert-butyl-1-methylbenzene 
• 26670-89-3 2-bromo-4-iodo-1-methylbenzene 
• 65188-53-6 2-bromo-4-tert-butyl-1-ethenylbenzene 
• 107-19-7 propargyl alcohol 
• 25015-63-8 4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane 

Relevant articles and documents

Copper-catalyzed recycling of halogen activating groups via 1,3-halogen migration

A Cu(I)-catalyzed 1,3-halogen migration reaction effectively recycles an activating group by transferring bromine or iodine from a sp2 to a benzylic carbon with concomitant borylation of the Ar-X bond. The resulting benzyl halide can be reacted in the same vessel under a variety of conditions to form an additional carbon-heteroatom bond. Cross-over experiments using an isotopically enriched bromide source support intramolecular transfer of Br. The reaction is postulated to proceed via a Markovnikov hydrocupration of the o-halostyrene, oxidative addition of the resulting Cu(I) complex into the Ar-X bond, reductive elimination of the new sp3 C-X bond, and final borylation of an Ar-Cu(I) species to turn over the catalytic cycle.