141037-91-4Relevant articles and documents
Cross aldolization reactions in furane series by means of silyl enol ethers
Le Roux,Maraval,Borredon,Gaspard-Iloughmane,Dubac
, p. 1053 - 1054 (1992)
The catalytic cross aldol reaction between a silyl enol ether and an aldehyde has been applied to the furane series giving the ketols RCOCH2CHOHR' (R or R' = 2-furyl). Good results (with no resinification or crotonisation) have been obtained using bismuth
Vanadyl species-catalyzed complementary β-oxidative carbonylation of styrene derivatives with aldehydes
Yang, Wen-Chieh,Weng, Shiue-Shien,Ramasamy, Anandhan,Rajeshwaren, Gobi,Liao, Yi-Ya,Chen, Chien-Tien
supporting information, p. 2385 - 2392 (2015/03/04)
A series of oxometallic species and metal acetylacetonates (acac) was examined as catalysts for oxidative carbonylation of styrene with benzaldehyde using t-butylhydroperoxide as the co-oxidant in warm acetonitrile. Among them, VO((acac)2 and vanadyl(iv) chloride were found to be the only catalyst class to achieve cross-coupling processes by judiciously tuning the ligand electronic attributes, leading to β-hydroxylation- and β-peroxidation-carbonylation of styrene, respectively, in a complementary manner. Mechanistic studies indicated that vanadyl-associated acyl radicals generated by t-butoxy radical-assisted, homolytic cleavage of the aldehyde C-H bond were involved in tandem processes with an exclusive syn diastereoselectivity in the case of β-methylstyrene. This journal is
Biomimetic hydrogenation: A reusable NADH co-enzyme model for hydrogenation of α,β-epoxy ketones and 1,2-diketones
Huang, Qiang,Wu, Ji-Wei,Xu, Hua-Jian
supporting information, p. 3877 - 3881 (2013/07/05)
A biomimetic method has been developed to transform α,β-epoxy ketones or 1,2-diketones into corresponding β-hydroxy ketones or α-hydroxy ketones using a catalytic amount of BNAH or BNA +Br-. The regeneration of BNAH or BNA+Br - is achieved by a mixture of HCOOH/Et3N. A radical mechanism is proposed to explain these observations.