144603-32-7

Basic information

• Product Name: 2,4(1H,3H)-Quinolinedione, 3-chloro-3-phenyl-
• CAS NO: 144603-32-7
• Molecular Formula: C15H10ClNO2
• Molecular Weight: 271.703
• Mol File: 144603-32-7.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 2,4(1H,3H)-Quinolinedione, 3-chloro-3-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 2,4(1H,3H)-Quinolinedione, 3-chloro-3-phenyl-(144603-32-7)
• EPA Substance Registry System: 2,4(1H,3H)-Quinolinedione, 3-chloro-3-phenyl-(144603-32-7)

Safety Data

• Hazardous Substances Data: 144603-32-7(Hazardous Substances Data)

Upstream product

• 14933-29-0 4-hydroxy-3-phenyl-2(1H)-quinolone 

Downstream Products

• 14933-29-0 4-hydroxy-3-phenyl-2(1H)-quinolone 
• 28565-95-9 3-hydroxy-3-phenylquinoline-2,4(1H,3H)-dione 
• 1303613-87-7 3-(4-(hydroxymethyl)-1H-1,2,3-triazol-1-yl)-3-phenylquinoline-2,4(1H,3H)-dione 
• 1303613-86-6 3-phenyl-3-(4-phenyl-1H-1,2,3-triazol-1-yl)quinoline-2,4(1H,3H)-dione 
• 1432733-36-2 1,2-dihydro-2-oxo-3-phenylquinolin-4-yl dihydrogen phosphate 
• 108832-15-1 2,4-dichloro-3-phenylquinoline 
• 477950-06-4 3-benzylamino-3-phenylquinoline-2,3(1H,3H)-dione 

Relevant articles and documents

Stereochemistry of the reduction of α-chloroketones with sodium borohydride—application to 3-chloroquinoline-2,4-diones: Dedicated to the memory of Professor Dr.?Vojeslav ?těrba who died in September 2015 being nearly 93 years old

3-Chloroquinoline-2,4-diones were reduced with sodium borohydride to give syn- and anti-chlorohydrins, the stereochemistry of which was established by NMR spectroscopy. Both stereoisomeric chlorohydrins were reacted with potassium carbonate in methanol. a

Reaction of some 2-quinolone derivatives with phosphoryl chloride: Synthesis of novel phosphoric acid esters of 4-hydroxy-2-quinolone

3-Chloroquinoline-2,4-diones do not react with phosphoryl chloride, however, 2,4-dichloroquinolines and/or 4-chloroquinolin-2-ones are formed in the presence of N,N-dimethylaniline. Along with these compounds, small quantities of novel dihydrogen phosphates of 4-hydroxyquinolin-2-ones were isolated. We outline a simple procedure that allows for the preparation of these compounds in moderate to good yields. All compounds were characterized by 1H and 13C NMR, IR, EI-MS, and ESI-MS spectroscopy, and in select cases by 31P NMR spectroscopy.