14696-82-3

Basic information

• Product Name: IODINEAZIDE
• Synonyms: IODINEAZIDE
• CAS NO: 14696-82-3
• Molecular Formula: IN₃
• Molecular Weight: 168.93
• Mol File: 14696-82-3.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: IODINEAZIDE(CAS DataBase Reference)
• NIST Chemistry Reference: IODINEAZIDE(14696-82-3)
• EPA Substance Registry System: IODINEAZIDE(14696-82-3)

Safety Data

• RIDADR: 0473
• HazardClass: 1.1A
• Hazardous Substances Data: 14696-82-3(Hazardous Substances Data)

Usage

General Description

Iodineazide is a chemical compound comprised of iodine and azide ions. It is commonly used as a powerful yet unstable explosive in research laboratories and in some industrial applications. Iodineazide can also be used as a detonator in initiating explosive devices due to its sensitivity to heat, shock, and friction. However, it is extremely hazardous and should be handled with extreme caution, as it can decompose explosively with heat or impact. Additionally, iodineazide can release toxic fumes when heated, making it a very dangerous chemical to work with. Due to its hazardous nature, iodineazide is strictly regulated and should only be handled by trained professionals in controlled environments with proper safety precautions in place.

InChI:InChI=1/IN3/c1-3-4-2

Upstream product

• 22750-57-8 cesium azide 

Downstream Products

• 7782-79-8 hydrogen azide 
• 1158-51-6 triphenyltin azide 
• 106112-73-6 tris(p-chlorophenyl)antimony iodine azide 
• 106112-75-8 tris(p-fluorophenyl)antimony iodine azide 
• 106112-77-0 triphenylbismuth iodine azide 
• 70675-21-7 triphenylantimony azide 
• 106112-72-5 tri-p-tolylantimony iodine azide 
• 14127-50-5 triphenyllead azide 
• 894-07-5 triphenyllead iodide 
• 7553-56-2 iodine 
• 7782-68-5 iodic acid 
• 7727-37-9 nitrogen 
• 7681-82-5 sodium iodide 

Relevant articles and documents

The [ICNI]+ cation: A combined experimental and theoretical study. Reaction of [ICNI]+[AsF6]- with CsN3

(Iodocyano)iodine hexafluoroarsenate, [ICNI]+[AsF6]-, containing the linear 22-valence-electron [ICNI]+ cation was synthesized either by the reaction of iodine cyanide with [I3]+[AsF6]- or directly from ICN, I2 and AsF5 and characterized by chemical analysis, IR, Raman and 19F NMR data. A combined vibrational (IR, Raman) and theoretical study revealed the [ICNI]+ cation to be linear, the preference of the linear over the bent structure can easily be understood in terms of hyperconjugative interactions in the cationic species [natural bond order (NBO) analysis]. The molecular structure of the [ICNI]+ cation was computed semiempirically (Austin Model 1, AMI; reparameterization of AM1, PM3) and ab initio at the Hartree-Fock (HF/6-31G*) and correlated RMP2 (RMP, restricted Moller-Plesset) and RMP4(SDQ) levels of theory using quasi-relativistic pseudo-potentials (LANL2DZ) for the icdine atoms. The computed structural parameters at the highest level applied are: Cx, symmetry, RMP4(SDQ), d(I-C) = 2.001, d(C≡N) = 1.167, d/(N-I) = 2.021 A. The N-I bond dissociation enthalpy for [ICN-I]+ was calculated ab initio at the electron-correlated RMP2 level of theory as 207.4 kJ mol-1. The metathetical reaction of [ICNI]+[AsF6]- with CsN3 in SO2ClF afforded IN3, Cs+[AsF6]- and ICN.