15082-42-5

Basic information

• Product Name: Benzenemethanol, lithium salt
• CAS NO: 15082-42-5
• Molecular Formula: C7H8O.Li
• Molecular Weight: 114.073
• Mol File: 15082-42-5.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: Benzenemethanol, lithium salt(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenemethanol, lithium salt(15082-42-5)
• EPA Substance Registry System: Benzenemethanol, lithium salt(15082-42-5)

Safety Data

• Hazardous Substances Data: 15082-42-5(Hazardous Substances Data)

Upstream product

• 100-51-6 benzyl alcohol 
• 119-61-9 benzophenone 
• 100-52-7 benzaldehyde 

Downstream Products

• 54060-36-5 2-chloro-1,2-diphenylethanol 
• 67210-34-8 1-phenyl-2-phenylsulfanyl-ethanol 
• 79345-14-5 <<(Phenylmethoxy)methyl>thio>benzene 
• 2612-36-4 2,2-dichloro-1-phenylethanol 
• 152428-84-7 (2S,3R,4S)-4-Benzyloxy-3-methyl-hexan-2-ol 
• 114507-46-9 (Z)-2-(2,3-benzo-2-cyclohexylidene)-1-phenylethanol 
• 114507-45-8 (E)-2-(2,3-benzo-2-cyclohexylidene)-1-phenylethanol 
• 178395-72-7 (2S,3R)-3-(tert-Butyl-dimethyl-silanyloxy)-2-(1,3-dioxo-1,3-dihydro-isoindol-2-ylmethyl)-butyric acid benzyl ester 
• 42406-36-0 (S)-benzyl 2-(1,3-dioxoisoindolin-2-yl)propanoate 
• 1026228-67-0 (S)-2-(1-Benzyl-2-methyl-1H-indol-4-yloxy)-propionic acid benzyl ester 
• 1027550-40-8 (S)-2-(1-Benzyl-2-ethyl-1H-indol-4-yloxy)-propionic acid benzyl ester 
• 191277-30-2 3-benzyloxy-Δ²-isoxazoline 
• 190083-63-7 (1S,2S)-2-Acetoxy-4-methyl-cyclohex-3-enecarboxylic acid benzyl ester 
• 90819-99-1 (-)-benzyl-(1S,2S,3R,4R)-3-methylbicyclo[2.2.1]hept-5-ene-2-carboxylate 

Relevant articles and documents

Developing Lithium Chemistry of 1,2-Dihydropyridines: From Kinetic Intermediates to Isolable Characterized Compounds

Generally considered kinetic intermediates in addition reactions of alkyllithiums to pyridine1-lithio-2-alkyl-1,2-dihydropyridines have been rarely isolated or characterized. This study develops their "isolated" chemistry. By a unique stoichiometric (that is1:1alkyllithium/pyridine ratios) synthetic approach using tridentate donors we show it is possible to stabilize and hence crystallize monomeric complexes where alkyl is tert-butyl. Theoretical calculations probing the donor-free parent tert-butyl species reveal 12 energetically similar stereoisomers in two distinct cyclotrimeric (LiN)3 conformations. NMR spectroscopy studies (including DOSY spectra) and thermal volatility analysis compare new sec-butyl and iso-butyl isomers showing the former is a hexane soluble efficient hydrolithiation agent converting benzophenone to lithium diphenylmethoxide. Emphasizing the criticalness of stoichiometryreaction of nBuLi/Me6TREN with two equivalents of pyridine results in non-alkylated 1-lithio-1,4-dihydropyridine·Me6TREN and 2-n-butylpyridineimplying mechanistically the kinetic 1,2-n-butyl intermediate hydrolithiates the second pyridine.

Experimental and computational studies of borohydride catalyzed hydrosilylation of a variety of C=O and C=N functionalities including esters, amides and heteroarenes

Sodium borohydride and a series of related borohydrides catalyze a transition metal-free hydrosilylation of a variety of C=O and C=N functionalities under mild conditions. Importantly, many of these reactions are possible using the cheap and environmentally benign hydrosilane polymethylhydrosiloxane. A mechanism is proposed based on experimental and computational results.

NAPHTHYRIDINES WHICH AFFECT IL-4 AND G-CSF

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