67210-34-8

Basic information

• Product Name: (S)-(-)-(2-hydroxy-2-phenyl-1-ethyl)-phenyl thioether
• CAS NO: 67210-34-8
• Molecular Weight: 230.331
• Mol File: 67210-34-8.mol
• Article Data: 74

Chemical Properties

• CAS DataBase Reference: (S)-(-)-(2-hydroxy-2-phenyl-1-ethyl)-phenyl thioether(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-(-)-(2-hydroxy-2-phenyl-1-ethyl)-phenyl thioether(67210-34-8)
• EPA Substance Registry System: (S)-(-)-(2-hydroxy-2-phenyl-1-ethyl)-phenyl thioether(67210-34-8)

Safety Data

• Hazardous Substances Data: 67210-34-8(Hazardous Substances Data)

Upstream product

• 16222-10-9 1-phenyl-2-(phenylthio)ethanone 
• 96-09-3 styrene oxide 
• 108-98-5 thiophenol 
• 100-42-5 styrene 
• 4551-15-9 phenylthiotrimethylsilane 
• 882-33-7 diphenyldisulfane 
• 592-41-6 1-hexene 
• 7205-91-6 phenylthiomethyl chloride 
• 15082-42-5 lithium benzyloxide 
• 49639-26-1 erythro-2-(phenylsulfinyl)-1-phenyl-1-ethanol 
• 100-52-7 benzaldehyde 
• 17873-08-4 (phenylsulfanylmethyl)trimethylsilane 
• 487-68-3 mesytaldehyde 
• 13307-75-0 (phenylthio)methyllithium 

Downstream Products

• 54681-09-3 1-bromo-1-phenyl-2-phenylthioethane 
• 100-52-7 benzaldehyde 
• 224634-51-9 S-α-phenylsulfonylmethylbenzyl alcohol 
• 49639-26-1 erythro-2-(phenylsulfinyl)-1-phenyl-1-ethanol 
• 18335-34-7 syn-4,4-dimethyl-1-phenylpentane-1,3-diol 
• 132157-40-5 (1R*,3R*)-4,4-Dimethyl-1-phenyl-1,3-pentanediol 
• 104174-42-7 (±)-1-methyl-4-phenylbutane-2,4-diol 
• 105769-47-9 (S)-(-)-2-chloro-2-phenylethyl phenyl sulfone 
• 16162-51-9 (S)-(-)-(2-hydroxy-2-phenyl-1-ethyl)-phenyl thioether 
• 3406-03-9 2-(phenylsulfonyl)acetophenone 
• 1445-91-6 (S)-1-phenylethanol 
• 1517-69-7 (R)-1-phenylethanol 
• 100-68-5 methyl-phenyl-thioether 
• 51755-92-1 β-phenyl-β-hydroxyethyl phenyl sulfone 

Relevant articles and documents

Solvent-mediated switching between oxidative addition and addition-oxidation: Access to β-hydroxysulfides and β-arylsulfones by the addition of thiols to olefins in the presence of Oxone

The reaction between aryl olefins and thiols in the presence of Oxone in toluene-water (9:1, v/v) affords β-hydroxy-2-arylethyl aryl sulfides smoothly by the interception of intermediary thiyl radicals with aryl olefins; the former are generated by the ox

Synthesis and application of Cu(II) immobilized MCM-41 based solid Lewis acid catalyst for aminolysis reaction under solvent-free condition

In this paper, a Cu(II) immobilized periodic mesoporous organosilica (PMOs) was synthesized and used as a reusable solid Lewis acid catalyst for the aminolysis of epoxides under solvent-free conditions. An amide-based ligand, L-propylsilyl (1) having a specific binding pocket was prepared and fabricated on mesoporous MCM-41 to produce mesoporous organosilica L-propylsilyl@MCM-41 (2). Further, it has been utilized for anchoring Cu(II) ions under controlled reaction conditions to yield solid Lewis acid catalyst Cu(II)-L-propylsilyl@MCM-41 (3). The synthesized catalyst 3 exhibits significantly higher catalytic activity for aminolysis compared to hitherto known solid Lewis acid catalysts. An extensive range of β-amino alcohols with high regio and stereoselectivity were prepared by using catalyst 3. The catalyst was recovered easily and reused eight times without any loss in its catalytic activity. Furthermore, the synthesis of clinically significant propranolol (β-blocker) from α- naphthyl glycidyl ether was attained successfully using catalyst 3 in a very decent yield.

Air-Induced Disulfenylation of Alkenes: Facile Synthesis of Vicinal Dithioethers

A novel disulfenylation of alkenes with thiophenols and their corresponding disulfides by using air as the oxidant has been achieved. This transformation provides a facile and practical protocol for the synthesis of vicinal dithioethers under mild conditions.