153255-45-9Relevant articles and documents
Reactions of β-diketiminate-stabilized calcium amides with 9-borabicyclo[3.3.1]nonane (9-BBN)
Barrett, Anthony G.M.,Crimmin, Mark R.,Hill, Michael S.,Hitchcock, Peter B.,Procopiou, Panayiotis A.
, p. 4076 - 4079 (2007)
The reaction of a β-diketiminate-stabilized calcium diphenylamide with the dialkylborane 9-BBN allows the synthesis of a β-diketiminate- stabilized calcium borohydride along with an amidoborane reaction coproduct via a likely σ-bond metathesis mechanism.
Alkaline-Earth-Catalyzed Dehydrocoupling of Amines and Boranes
Liptrot, David J.,Hill, Michael S.,Mahon, Mary F.,Wilson, Andrew S. S.
supporting information, p. 13362 - 13365 (2015/11/09)
Dehydrocoupling reactions between the boranes HBpin and 9-borabicyclo[3.3.1]nonane and a range of amines and anilines ensue under very mild reaction conditions in the presence of a simple β-diketiminato magnesium n-butyl precatalyst. The facility of the reactions is suggested to be a function of the Lewis acidity of the borane substrate, and is dictated by resultant pre-equilibria between, and the relative stability of, magnesium hydride and borohydride intermediates during the course of the catalysis.