15475-27-1

Basic information

• Product Name: POTASSIUM DIPHENYLPHOSPHIDE
• Synonyms: Potassium diphenylphosphide solution,Diphenylphosphine potassium salt;Potassium diphenylphosphide solution 0.5 in THF;KPPh2;Potassium diphenylphosphine;DIPHENYLPHOSPHINE POTASSIUM SALT;POTASSIUM DIPHENYLPHOSPHIDE;potassium diphenylphosphide solution;POTASSIUM DIPHENYLPHOSPHIDE SOLUTION, ~0 .5 M IN THF
• CAS NO: 15475-27-1
• Molecular Formula: C₁₂H₁₀KP
• Molecular Weight: 224.28
• Mol File: 15475-27-1.mol
• Article Data: 18

Chemical Properties

• Flash Point: −4 °F
• Appearance: /
• Density: 0.929 g/mL at 25 °C
• BRN: 4164304
• CAS DataBase Reference: POTASSIUM DIPHENYLPHOSPHIDE(CAS DataBase Reference)
• NIST Chemistry Reference: POTASSIUM DIPHENYLPHOSPHIDE(15475-27-1)
• EPA Substance Registry System: POTASSIUM DIPHENYLPHOSPHIDE(15475-27-1)

Safety Data

• Hazard Codes: F,C
• Statements: 11-19-22-34-40-37
• Safety Statements: 16-26-33-36/37/39-45
• RIDADR: UN 2924 3/PG 2
• WGK Germany: 1
• F: 1-8-10-13
• Hazardous Substances Data: 15475-27-1(Hazardous Substances Data)

Usage

General Description

Potassium diphenylphosphide is a chemical compound with the formula KDP. It is a white to off-white solid that is insoluble in water and reacts with moisture. POTASSIUM DIPHENYLPHOSPHIDE is primarily used as a reagent in organic synthesis, particularly in the preparation of phosphines and phosphine oxides. It is a strong reducing agent, and as such, it can be used to reduce various functional groups in organic molecules. Additionally, potassium diphenylphosphide has been studied for its potential applications in the field of materials science, such as in the development of new types of polymers and other advanced materials. Overall, this compound has diverse chemical reactivity and potential applications in several different fields of chemistry.

Upstream product

• 829-85-6 diphenylphosphane 
• 4376-01-6 sodium diphenylphosphide 
• 1031-93-2 diphenyl(p-tolyl)phosphine 
• 1372549-38-6 1-tert-butyl-3-methyl-4-diphenylphosphinoimidazole-2-thione 
• 1079-66-9 chloro-diphenylphosphine 
• 17154-34-6 (trimethylsilyl)diphenylphosphine 
• 603-35-0 triphenylphosphine 

Downstream Products

• 4848-43-5 (2-aminoethyl)diphenylphosphane 
• 2360-09-0 γ-diphenylphosphinopropyl alcohol 
• 2360-12-5 (2-hydroxy-2-phenylethyl)diphenylphosphine 
• 30853-95-3 Bis-(2-diphenylphosphanyl-ethyl)-(3-methoxy-propyl)-amine 
• 98739-90-3 4-methoxy-1,1-diphenyl-phosphinanium; bromide 
• 32564-56-0 N-(2-Diphenylphosphanyl-ethyl)-N',N'-diethyl-N-propyl-ethane-1,2-diamine 
• 2652-63-3 1-diphenylphosphanylpropan-2-ol 
• 96548-46-8 <5,5'-(1,7-dithia-4,10-diazacyclododecane-4,10-diyl)bis(3-oxapentyl)>bis(diphenylphosphine) 
• 16605-03-1 (3-aminopropyl)diphenylphosphine 
• 136514-31-3 N,N,N'N'-Tetrakis<2-(diphenylphosphino)ethyl>ethane-1,2-diamine 
• 116156-85-5 (R)-(+)-2,3-O-isopropylideneglycerol-1-diphenylphosphane 
• 162616-46-8 (3-phenylpropyl)diphenylphosphine 
• 201011-40-7 1-[4-(diphenylphosphino)phenyl]methanamine 
• 169052-23-7 (4-diethylphosphono)phenyl-diphenylphosine 

Relevant articles and documents

Extremely bulky secondary phosphinoamines as substituents for sterically hindered aminosilanes

The synthesis of a series of extremely bulky secondary amines with a phosphine function, Ar?(PR2)NH (Ar? = C6H2{C(H)Ph2}2Pri-2,6,4; R = Ph, NEt2, NPri

Alkali-metal-catalyzed addition of primary and secondary phosphines to carbodiimides. A general and efficient route to substituted phosphaguanidines

Organo alkali metal compounds such as nBuLi and (Me 3Si)2NK act as excellent catalyst precursors for the addition of phosphine P-H bonds to carbodiimides, offering a general and atom-economical route to substituted phospha

Eine einfache Methode zur Darstellung von Alkalimetall-bis(trimethylsilyl)phosphiden

A simple way for the preparation of alkali-bis(trimethylsilyl)phosphides is described by the reaction of tris(trimethylsilyl)phosphine with alkali-alcoholates.

N?H Bond Formation at a Diiron Bridging Nitride

Despite their connection to ammonia synthesis, little is known about the ability of iron-bound, bridging nitrides to form N?H bonds. Herein we report a linear diiron bridging nitride complex supported by a redox-active macrocycle. The unique ability of th

Synthesis and properties of heterobimetallic rhodium complexes featuring LiI, CuI or ZnII as a Lewis acidic metalloligand

A series of [(PMP)Rh(CO)Cl]n+ complexes was synthesised and the impact of the metalloligands CuI, LiI and ZnII on the CO stretching band was analysed.