2360-12-5Relevant articles and documents
CsOH-promoted epoxide ring-opening with phosphines: Mild and efficient synthesis of monohydroxyphosphines
Fox, Daniel L.,Robinson, Ashlee A.,Frank, James B.,Salvatore, Ralph Nicholas
, p. 7579 - 7582 (2007/10/03)
A mild and convenient synthesis of monohydroxyphosphines has been achieved by epoxide ring-opening using primary or secondary phosphines in the presence of cesium hydroxide, 4 ? molecular sieves and DMF at room temperature. These reaction conditions were
2-Hydroxyalkyl Diphenylphosphines: Biocatalytic Resolution and Use as Ligands for Transition-metal Catalysts
Kagan, Henri B.,Tahar, Maurice,Fiaud, Jean-Claude
, p. 5959 - 5962 (2007/10/02)
Kinetic resolution of 2-hydroxyalkyldiphenylphosphines 1 by acylation with isopropenyl acetate was carried out under rabbit gastric lipase (RGL) catalysis to give optically active 1 and the corresponding acetate, the enantioselectivity factors E ranging from 10 to 20. Key words: 2-hydroxyalkyldiphenylphosphines; rabbit gastric lipase; kinetic resolution; biocatalysis; acylation
SIMPLE METHOD FOR GENERATING SUBSTITUTED PHOSPHIDE AND PHOSPHINITE ANIONS AND SYNTHESES BASED ON THEM
Tsvetkov, E. N.,Bondarenko, N. A.,Malakhova, I. G.,Kabachnik, M. I.
, p. 8 - 22 (2007/10/02)
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