157860-90-7Relevant articles and documents
Dinuclear Manganese and Rhenium Complexes with Mixed Aliphatic-Aromatic Hydrocarbon Bridges
Lindner, Ekkehard,Wassing, Walter,Fawzi, R.,Steimann, M.
, p. 1651 - 1660 (2007/10/02)
The symmetrically hydrocarbon-bridged complexes (OC)5M-(CH2)n+1-X-(CH2)n+1-M(CO)5 are obtained by the reaction of the bistriflates X2 with the carbonyl metalates (1-) (M = Mn, Re) in THF and dimethyl ether, respectively.According to an X-ray structural analysis 8a crystallizes in the triclinic space group P with Z = 2.Depending on the solvent, the reaction of 7a with (1-) affords also the cyclic carbene complex 10a.The behavior of the manganese compounds toward CO has been investigated exemplarily in the case of 8a and leads to the diacyl complex 1,2-C6H42 (11).Upon reaction with Na2CO3/CH3OH 11 is converted to give the corresponding diester 1,2-C6H42 (12).Key words: Bistriflates, Hydrogen-Bridged Complexes, Manganese Complexes, Rhenium Complexes, Crystal Structure