15917-77-8

Basic information

• Product Name: NITRIC-15N OXIDE
• Synonyms: NITRIC-15N OXIDE;NITROGEN-15N MONOXIDE;NITRIC-15N OXIDE, 98 ATOM % 15N;NITRIC OXIDE (15N, 98%+)
• CAS NO: 15917-77-8
• Molecular Formula: NO
• Molecular Weight: 31.02
• Mol File: 15917-77-8.mol
• Article Data: 4

Chemical Properties

• Melting Point: −163.6 °C(lit.)
• Boiling Point: −151.7 °C(lit.)
• Appearance: /
• CAS DataBase Reference: NITRIC-15N OXIDE(CAS DataBase Reference)
• NIST Chemistry Reference: NITRIC-15N OXIDE(15917-77-8)
• EPA Substance Registry System: NITRIC-15N OXIDE(15917-77-8)

Safety Data

• Hazard Codes: T
• Statements: 23/24/25-34-44
• Safety Statements: 23-36/37/39-45
• RIDADR: UN 1760 8/PG 2
• Hazardous Substances Data: 15917-77-8(Hazardous Substances Data)

Upstream product

• 68378-96-1 sodium ⁽¹⁵⁾N-nitrite 
• 106-53-6 para-bromobenzenethiol 
• 14390-96-6 ammonia 

Downstream Products

• 14184-22-6 ⁽¹⁵⁾N-nitrogen dioxide 
• 29817-79-6 nitrogen-15 
• 17787-11-0 nitrogen 
• 20509-24-4 (14,15)NO 
• 7727-37-9 nitrogen 
• 10024-97-2 dinitrogen monoxide 
• 20621-02-7 ⁽¹⁵⁾N-nitrous oxide 
• 22364-56-3 ammonia-⁽¹⁵⁾N-d3 
• 7789-20-0 water-d2 
• 1173020-41-1 dinitrogen 
• 1111-72-4 carbon dioxide 
• 80937-33-3 oxygen 
• 10102-43-9 nitrogen(II) oxide 
• 1173020-41-1 ⁽¹⁴⁾-nitrogen 

Relevant articles and documents

Direct NO Reduction by a Biomimetic Iron(II) Pyrazolate MOF

A novel metal-organic framework (MOF) containing one-dimensional, Fe2+ chains bridged by dipyrazolate linkers and N,N-dimethylformamide (DMF) ligands has been synthesized. The unusual chain-type metal nodes feature accessible coordination sites on adjacent metal centers, resulting in motifs that are reminiscent of the active sites in non-heme diiron enzymes. The MOF facilitates direct reduction of nitric oxide (NO), producing nearly quantitative yields of nitrous oxide (N2O) and emulating the reactivity of flavodiiron nitric oxide reductases (FNORs). The ferrous form of the MOF can be regenerated via a synthetic cycle involving reduction with cobaltocene (CoCp2) followed by reaction with trimethylsilyl triflate (TMSOTf).

Structure, Harmonic Force Field and Hyperfine Coupling Constants of Nitrosyl Chloride

The pure rotational spectra of five isotropic species of nitrosyl chloride were measured using a cavity pulsed microwave Fourier-transform spectometer.Some a-type transitions of all five isotopomers, and some weak b-type transitions of four of these isotopomers were measured in the 4-26 GHz frequency range.Precise values for the rotational constants and the quartic centrifugal distortion constants were obtained.The rotational constants were used in structure determinations and the centrifugal distortion constants were used in a refinement of the harmonic general valence force field.A harmonic central valence force field was also calculated.Hyperfine structure in these transitions arising from quadrupole and spin-rotation coupling interactions was also observed.Diagonal and off-diagonal quadrupole coupling constants and diagonal spin-rotation coupling constants of both the chlorine and nitrogen nuclei were determined.The principal quadrupole coupling constants were evaluated and used to calculate the approximate ionic character of the N-Cl bond.The spin-rotational coupling constants were used to calculate the diamagnetic shielding factor for the nitrogen nucleus; the magnitude of this value indicates a fairly ionic N-Cl bond.