1598409-43-8

Basic information

• Product Name: cis-Pd(OCOCF₃)(2-phenylbenzyl)(dppe)
• Synonyms: cis-Pd(OCOCF₃)(2-phenylbenzyl)(dppe)
• CAS NO: 1598409-43-8
• Molecular Weight: 785.09
• Mol File: 1598409-43-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: cis-Pd(OCOCF₃)(2-phenylbenzyl)(dppe)(CAS DataBase Reference)
• NIST Chemistry Reference: cis-Pd(OCOCF₃)(2-phenylbenzyl)(dppe)(1598409-43-8)
• EPA Substance Registry System: cis-Pd(OCOCF₃)(2-phenylbenzyl)(dppe)(1598409-43-8)

Safety Data

• Hazardous Substances Data: 1598409-43-8(Hazardous Substances Data)

Upstream product

• 2928-43-0 2-biphenylmethanol 
• 947-84-2 2-Biphenylcarboxylic acid 
• 1598409-40-5 2-phenylbenzyl trifluoroacetate 
• 19978-61-1 (1,2-bis(diphenylphosphanyl)ethane)dichloridopalladium(II) 

Downstream Products

• 86-73-7 9H-fluorene 

Relevant articles and documents

Direct access to fluorene by successive C-O/C-H bond activations of 2-phenylbenzyl ester

Catalytic formation of fluorene has been achieved from 2-phenylbenzyl trifluoroacetate via successive C-O and C-H bond cleavage reactions by Pd(OAc)2/PPh3 in 97% yield. This reaction involves the oxidative addition of ester to give (carboxylato)(2-phenylbenzyl)palladium(II) species and deprotonation from the 2-phenylbenzyl group by the cleaved carboxylato group via an internal electrophilic substitution mechanism.