1619829-61-6

Basic information

• Product Name: N-allyl-N-(1-(2-bromophenyl)-3-(naphthalen-1-yl)prop-2-yn-1-yl)benzamide
• Synonyms: N-allyl-N-(1-(2-bromophenyl)-3-(naphthalen-1-yl)prop-2-yn-1-yl)benzamide
• CAS NO: 1619829-61-6
• Molecular Weight: 480.404
• Mol File: 1619829-61-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N-allyl-N-(1-(2-bromophenyl)-3-(naphthalen-1-yl)prop-2-yn-1-yl)benzamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-allyl-N-(1-(2-bromophenyl)-3-(naphthalen-1-yl)prop-2-yn-1-yl)benzamide(1619829-61-6)
• EPA Substance Registry System: N-allyl-N-(1-(2-bromophenyl)-3-(naphthalen-1-yl)prop-2-yn-1-yl)benzamide(1619829-61-6)

Safety Data

• Hazardous Substances Data: 1619829-61-6(Hazardous Substances Data)

Upstream product

• 15727-65-8 1-ethynylnaphthalene 
• 98-88-4 benzoyl chloride 
• 183864-20-2 N-[(2-bromophenyl)methylidene]-N-(2-propenyl)amine 

Relevant articles and documents

Modular strategy for the synthesis of functionalized aryl-fused azabicyclo[2.2.2]octanes via radical-mediated cascade cyclization

A two-step synthesis of rare 2-azabicyclo[2.2.2]octanes is described. N-propargyl amides obtained via Cu(I)-catalyzed three-component coupling, underwent radical-mediated cascade cyclization to afford 5,6-aryl-fused 2-azabicyclo[2.2.2]octanes with arylidene functionality on the two-carbon bridge in 43-62% yields. Phenylidene and 1-naphtylidene derivatives were obtained exclusively as Z diastereomers, whereas electron rich groups in the arylidene substituent afforded product mixtures favoring the Z diastereomer by 2.3:1 M ratio.