1666-14-4Relevant articles and documents
Enantioselective Synthesis of Axially Chiral Benzothiophene/Benzofuran-Fused Biaryls by N-Heterocyclic Carbene Catalyzed Arene Formation
Zhang, Chun-Lin,Gao, Yuan-Yuan,Wang, Hai-Ying,Zhou, Bang-An,Ye, Song
supporting information, p. 13918 - 13922 (2021/05/18)
Axially chiral biaryl scaffolds are prevalent in natural products, chiral ligands, and organocatalysts. However, N-heterocyclic carbene (NHC) catalyzed de novo construction of an aromatic ring with concomitant axial chirality induction for the synthesis o
Sterically Demanding AgI and CuI N-Heterocyclic Carbene Complexes: Synthesis, Structures, Steric Parameters, and Catalytic Activity
Cervantes-Reyes, Alejandro,Rominger, Frank,Hashmi, A. Stephen K.
supporting information, p. 5530 - 5540 (2020/05/05)
The synthesis and full characterization of new air-stable AgI and CuI complexes bearing structurally bulky expanded-ring N-heterocyclic carbene (erNHC) ligands is presented. The condensation of protonated NHC salts with Ag2/sub
Dearomative Dienolate-Mediated Catalysis: A Remote Activation Strategy for Asymmetric Functionalization of Benzylic C-H Bonds of Heteroaryl Aldehydes
Wang, Yang,Lin, Jun-Bing,Xie, Ji-Kang,Lu, Hong,Hu, Xiu-Qin,Xu, Peng-Fei
supporting information, p. 5835 - 5839 (2018/09/25)
A dearomative remote activation strategy for the asymmetric functionalization of benzylic C-H bonds of heteroaryl aldehydes under bifunctional Br?nsted base catalysis has been developed. The in situ generated o-QDMs-type dienolate intermediates were effic
