16744-89-1

Basic information

• Product Name: 2-METHYL-5-HEXEN-2-OL
• Synonyms: 2-METHYL-5-HEXENE-2-OL;2-METHYL-5-HEXEN-2-OL;5-Hexen-2-ol, 2-methyl-;2-methylhex-5-en-2-ol
• CAS NO: 16744-89-1
• Molecular Formula: C₇H₁₄O
• Molecular Weight: 114.19
• Mol File: 16744-89-1.mol
• Article Data: 19

Chemical Properties

• Melting Point: 26°C (estimate)
• Boiling Point: 178.73°C (estimate)
• Flash Point: 56.5°C
• Appearance: /
• Density: 0.8596 (estimate)
• Vapor Pressure: 2.26mmHg at 25°C
• Refractive Index: 1.4320 (estimate)
• CAS DataBase Reference: 2-METHYL-5-HEXEN-2-OL(CAS DataBase Reference)
• NIST Chemistry Reference: 2-METHYL-5-HEXEN-2-OL(16744-89-1)
• EPA Substance Registry System: 2-METHYL-5-HEXEN-2-OL(16744-89-1)

Safety Data

• Hazardous Substances Data: 16744-89-1(Hazardous Substances Data)

Usage

InChI:InChI=1/C7H14O/c1-4-5-6-7(2,3)8/h4,8H,1,5-6H2,2-3H3

Upstream product

• 516-79-0 provitamin D₄ 
• 67-64-1 acetone 
• 186581-53-3 diazomethane 
• 917-64-6 methyl magnesium iodide 
• 591-80-0 pent-4-enoic acid 
• 7103-09-5 4-but-1-enylmagnesium bromide 
• 109-49-9 5-Hexen-2-one 
• 690-94-8 dimethyl(vinylethynyl)carbinol 
• 64-17-5 ethanol 
• 5162-44-7 1-bromo-4-butene 
• 287-92-3 Cyclopentane 
• 75-16-1 methylmagnesium bromide 
• 1968-40-7 ethyl 4-pentenoate 
• 60-29-7 diethyl ether 

Downstream Products

• 4049-81-4 2-methyl-1,5-hexadiene 
• 203069-95-8 Diphenyl(2-methylhex-5-en-2-yloxy)silane 
• 1621999-28-7 (S)-5-(3,3-diphenylallyl)-2,2-dimethyltetrahydrofuran 
• 1621999-44-7 (S,E)-5-(3-(4-(tert-butyl)phenyl)allyl)-2,2-dimethyltetrahydrofuran 
• 1036403-84-5 (1,1-dimethylpent-4-enyl)carbamic acid benzyl ester 
• 1620886-68-1 (Z)-3-chloro-2-((5,5-dimethyltetrahydrofuran-2-yl)methyl)-3-phenylacrylamide 
• 201020-16-8 ((C₁₃H₁₅N₂)2)Zr(OC(CH₃)2CH₂CH₂CHCH₂)⁽¹⁺⁾*B(C₆F₅)4^(1-)=[((C₁₃H₁₅N₂)2)Zr(C₇H₁₃O)][B(C₆F₅)4] 
• 58203-68-2 2,2-dimethylhex-5-enoic acid 
• 56068-50-9 2,2-dimethylhex-5-en-1-ol 
• 7116-86-1 5,5-dimethyl-hex-1-ene 
• 4535-54-0 2,2-dimethyl-6-phenyl-tetrahydro-pyran 

Relevant articles and documents

Cyclopentanone ring expansion leading to functionalized δ-lactams: Short synthesis of simple sedum alkaloids

Equation Presented Monosubstituted epoxides react with (cyclopentenyloxy) trimethylsilane to afford, after subsequent oxidative fragmentation, a pair of diastereomeric 8-membered iodolactones. When these lactones are separately treated with sodium azide,

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A concise approach towards the synthesis of WS75624 a and WS75624 B via the cross-metathesis of vinyl-functionalized thiazoles

Synthetic approach towards precursors of WS75624 A and WS75624 B, two potent endothelin converting enzyme (ECE) inhibitors and potential antihypertensive agents, is reported featuring a key cross-metathesis between a vinyl-functionalized thiazole and a terminal olefin. As the two natural products only differ by the nature of their hydroxyalkyl side-chain, our convergent strategy enable the synthesis of key intermediates of both molecules in a limited amount of steps.