174265-12-4

Basic information

• Product Name: 2-Bromo-5-chlorobenzaldehyde
• Synonyms: 2-Bromo-5-chlorobenzaldehyde;5-Chloro-2-bromobenzaldehyde;2-Bromo-5-chlorobenzalde
• CAS NO: 174265-12-4
• Molecular Formula: C₇H₄BrClO
• Molecular Weight: 219.46
• EINECS: 1592732-453-0
• Product Categories: Adehydes, Acetals & Ketones;Bromine Compounds;Chlorine Compounds
• Mol File: 174265-12-4.mol
• Article Data: 17

Chemical Properties

• Melting Point: 66 °C
• Boiling Point: 258 °C
• Flash Point: 110 °C
• Appearance: Pale yellow/Crystalline
• Density: 1.698
• Vapor Pressure: 0.014mmHg at 25°C
• Refractive Index: 1.623
• Storage Temp.: Keep in dark place,Sealed in dry,Room Temperature
• Solubility: soluble in Methanol
• CAS DataBase Reference: 2-Bromo-5-chlorobenzaldehyde(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Bromo-5-chlorobenzaldehyde(174265-12-4)
• EPA Substance Registry System: 2-Bromo-5-chlorobenzaldehyde(174265-12-4)

Safety Data

• Hazard Codes: Xi,Xn
• Statements: 22
• Safety Statements: 24/25
• RIDADR: UN1993
• Hazardous Substances Data: 174265-12-4(Hazardous Substances Data)

Usage

General Description

2-Bromo-5-chlorobenzaldehyde, also known as 5-chloro-2-bromobenzaldehyde, is a chemical compound with the molecular formula C7H4BrClO. It is a white to off-white crystalline solid that is commonly used in organic synthesis as a building block for the preparation of various pharmaceuticals and agrochemicals. 2-Bromo-5-chlorobenzaldehyde is also used as an intermediate in the manufacture of dyes, pigments, and other organic compounds. It is an important reagent in the production of various organic compounds due to its versatile chemical properties and functional groups. 2-Bromo-5-chlorobenzaldehyde is known for its strong and distinct odor, and it is considered to be a hazardous chemical that should be handled with care and caution.

InChI:InChI=1/C7H4BrClO/c8-7-2-1-6(9)3-5(7)4-10/h1-4H

Synthetic route

2-bromo-5-chlorobenzyl alcohol (60666-70-8) → 2-bromo-5-chlorobenzaldehyde (174265-12-4)

Conditions	Yield
Stage #1: 2-bromo-5-chlorobenzyl alcohol With oxalyl dichloride; dimethyl sulfoxide In dichloromethane at -78℃; for 0.25h; Stage #2: With triethylamine In dichloromethane at -78 - 20℃;	96%
With triphenylmethyl alcohol; iron(III) chloride hexahydrate at 55℃; for 1h; Microwave irradiation;	85%
With triphenylmethyl alcohol; [bis(trifluoromethanesulfonyl)imidate](triphenylphosphine)gold(I) at 140℃; for 1h; Microwave irradiation;	85%
With Dess-Martin periodane In dichloromethane at 20℃; for 1h; Inert atmosphere;
Stage #1: 2-bromo-5-chlorobenzyl alcohol With oxalyl dichloride; dimethyl sulfoxide In dichloromethane at -78℃; for 0.0833333h; Stage #2: With triethylamine In dichloromethane at 0 - 20℃; for 4h;

1-bromo-4-chloro-2-dibromomethylbenzene (1313762-49-0) → 2-bromo-5-chlorobenzaldehyde (174265-12-4)

Conditions	Yield
With sulfuric acid at 60℃; for 3h; Inert atmosphere;	95%

2-bromo-5-chlorobenzyl bromide (66192-24-3) → 2-bromo-5-chlorobenzaldehyde (174265-12-4)

Conditions	Yield
With 4-methylmorpholine N-oxide In acetonitrile at 0℃; for 2h; Molecular sieve;	92%
With 4 A molecular sieve; 4-methylmorpholine N-oxide In acetonitrile at 0℃; for 2h;	65%

3-Chlorobenzaldehyde (587-04-2) → 2-bromo-5-chlorobenzaldehyde (174265-12-4)

Conditions	Yield
With N-Bromosuccinimide; sulfuric acid; iodine at 10 - 25℃; for 3h; Reagent/catalyst;	90.1%
With N-Bromosuccinimide; 4-chloro-2-(trifluoromethyl)aniline; palladium diacetate In 1,2-dichloro-ethane; trifluoroacetic acid at 60℃; for 24h;	88%
With N-Bromosuccinimide; palladium diacetate; silver trifluoroacetate; toluene-4-sulfonic acid; trifluoroacetic acid; 4-Nitroanthranilic acid In 1,2-dichloro-ethane at 90℃; for 24h; Sealed tube;	80%
Multi-step reaction with 3 steps 1: pyridine / dichloromethane / 1 h / 20 °C 2: N-Bromosuccinimide; Ag(1-)*C2F3O2(1-); palladium diacetate / 1,2-dichloro-ethane / 24 h / 120 °C 3: formaldehyd; toluene-4-sulfonic acid / tetrahydrofuran; water / 0.25 h / 100 °C / Microwave irradiation View Scheme

2-bromo-5-chlorobenzaldehyde O-methyloxime → 2-bromo-5-chlorobenzaldehyde (174265-12-4)

Conditions	Yield
With formaldehyd; toluene-4-sulfonic acid In tetrahydrofuran; water at 100℃; for 0.25h; Microwave irradiation;	86%

(2-bromo-5-chlorophenyl)methanediyl diacetate (882772-93-2) → 2-bromo-5-chlorobenzaldehyde (174265-12-4)

Conditions	Yield
With sulfuric acid In methanol; water for 0.5h; Reflux;	83%
With hydrogenchloride; water In 1,4-dioxane for 2.5h; Reflux;

3N-HCl + 2-bromo-5-chlorotoluene (14495-51-3) + chromium(VI) oxide (1333-82-0) → 2-bromo-5-chlorobenzaldehyde (174265-12-4)

Conditions	Yield
With sulfuric acid In ethanol; water; acetic anhydride	77%

2-bromo-5-chlorotoluene (14495-51-3) → 2-bromo-5-chlorobenzaldehyde (174265-12-4)

Conditions	Yield
Multi-step reaction with 2 steps 1: N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile) / benzene / 16 h / Reflux; Inert atmosphere 2: sulfuric acid / 3 h / 60 °C / Inert atmosphere View Scheme
Multi-step reaction with 2 steps 1: chromium(VI) oxide; acetic acid; sulfuric acid / 2 h / 0 °C 2: sulfuric acid / methanol; water / 0.5 h / Reflux View Scheme

2-bromo-5-chlorobenzoic acid (21739-93-5) → 2-bromo-5-chlorobenzaldehyde (174265-12-4)

Conditions	Yield
Multi-step reaction with 2 steps 1: borane dimethyl sulphide complex / tetrahydrofuran / 15 h / 0 - 20 °C / Inert atmosphere 2: Dess-Martin periodane / dichloromethane / 1 h / 20 °C / Inert atmosphere View Scheme
Multi-step reaction with 2 steps 1.1: borane-THF / tetrahydrofuran / 4 h / 0 - 20 °C / Inert atmosphere 2.1: dimethyl sulfoxide; oxalyl dichloride / dichloromethane / 0.25 h / -78 °C 2.2: -78 - 20 °C View Scheme

3-chlorobenzaldehyde O-methyloxime (33499-36-4) → 2-bromo-5-chlorobenzaldehyde (174265-12-4)

Conditions	Yield
Multi-step reaction with 2 steps 1: N-Bromosuccinimide; Ag(1-)*C2F3O2(1-); palladium diacetate / 1,2-dichloro-ethane / 24 h / 120 °C 2: formaldehyd; toluene-4-sulfonic acid / tetrahydrofuran; water / 0.25 h / 100 °C / Microwave irradiation View Scheme

sodium metaborate (7775-19-1) → 2-bromo-5-chlorobenzaldehyde (174265-12-4)

Conditions	Yield
bis(triphenylphosphine)palladium(II)-chloride In water

dihydroxyborane (13780-71-7) → 2-bromo-5-chlorobenzaldehyde (174265-12-4)

2-bromo-5-chlorobenzaldehyde (174265-12-4) → 2-bromo-5-chlorobenzyl alcohol (60666-70-8)

Conditions	Yield
With sodium tetrahydroborate In methanol at 0 - 20℃; for 1h;	100%
With sodium hydride In methanol at 20℃;	95%
With sodium borohydrid In methanol; water; acetone	94%

2-bromo-5-chlorobenzaldehyde (174265-12-4) + N,N-dimethylethylenediamine (108-00-9) → N'-(2-bromo-5-chlorobenzyl)-N,N-dimethylethane-1,2-diamine (886041-45-8)

Conditions	Yield
Stage #1: 2-bromo-5-chlorobenzaldehyde; N,N-dimethylethylenediamine With acetic acid In tetrahydrofuran at 20℃; for 1h; pH=5; Stage #2: With sodium cyanoborohydride In methanol at 20℃; for 3h; Stage #3: With water; sodium hydrogencarbonate In ethyl acetate	100%

2-bromo-5-chlorobenzaldehyde (174265-12-4) + Methyltriphenylphosphonium bromide (1779-49-3) → 1-bromo-4-chloro-2-vinylbenzene

Conditions	Yield
Stage #1: Methyltriphenylphosphonium bromide With potassium tert-butylate In tetrahydrofuran at 20℃; for 2h; Wittig Olefination; Stage #2: 2-bromo-5-chlorobenzaldehyde In tetrahydrofuran at 0 - 20℃; for 12h; Wittig Olefination;	100%
With potassium carbonate In 1,4-dioxane at 110℃; for 10h; Inert atmosphere;	79%
Stage #1: Methyltriphenylphosphonium bromide With n-butyllithium In tetrahydrofuran; hexane at 0 - 20℃; for 1.5h; Inert atmosphere; Stage #2: 2-bromo-5-chlorobenzaldehyde In tetrahydrofuran; hexane at 0 - 20℃; for 2h; Inert atmosphere;	60%

2-bromo-5-chlorobenzaldehyde (174265-12-4) + trimethylsilylacetylene (1066-54-2) → 5-chloro-2-[2-(trimethylsilyl)ethynyl]benzaldehyde

Conditions	Yield
With copper(l) iodide; tetrakis(triphenylphosphine) palladium(0); triethylamine at 20 - 70℃; Sonogashira Cross-Coupling; Inert atmosphere;	99%
Stage #1: 2-bromo-5-chlorobenzaldehyde With copper(l) iodide; triethylamine at 23℃; for 0.25h; Inert atmosphere; Stage #2: trimethylsilylacetylene With tetrakis(triphenylphosphine) palladium(0) at 20℃; Inert atmosphere;
With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine at 20℃; for 12h;

2-bromo-5-chlorobenzaldehyde (174265-12-4) + 3,5-Dimethoxyaniline (10272-07-8) → 7-chloro-1,3-dimethoxyacridine

Conditions	Yield
Stage #1: 3.5-dimethoxyaniline With 1,1'-bis-(diphenylphosphino)ferrocene; tris-(dibenzylideneacetone)dipalladium(0); potassium carbonate In toluene at 20℃; for 0.0833333h; Inert atmosphere; Stage #2: 2-bromo-5-chlorobenzaldehyde In toluene at 80℃; for 12h; Inert atmosphere;	99%

2-bromo-5-chlorobenzaldehyde (174265-12-4) + 2-(anthracene-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (676578-20-4) → C21H13ClO (1301205-51-5)

Conditions	Yield
With sodium carbonate; tetrakis(triphenylphosphine) palladium(0) In 1,2-dimethoxyethane; water for 11h; Suzuki-Miyaura Coupling; Reflux;	98%

2-bromo-5-chlorobenzaldehyde (174265-12-4) + trimethyl orthoformate (149-73-5) → 2-bromo-5-chlorobenzaldehyde dimethyl acetal (959687-69-5)

Conditions	Yield
With tropylium tetrafluoroborate In acetonitrile at 70℃; for 5h; Inert atmosphere; Green chemistry;	98%
With Montmollironite clay K-10 at 20℃; for 1.5h; Inert atmosphere;	77%
Stage #1: trimethyl orthoformate With montmorillonite clay k-10 at 20℃; for 0.333333h; Inert atmosphere; Stage #2: 2-bromo-5-chlorobenzaldehyde for 3h; Inert atmosphere;

2-bromo-5-chlorobenzaldehyde (174265-12-4) + ethylene glycol (107-21-1) → 2-(2-bromo-5-chlorophenyl)-1,3-dioxolane (1187647-98-8)

Conditions	Yield
With toluene-4-sulfonic acid In toluene for 12h; Inert atmosphere; Dean-Stark; Reflux;	98%
With toluene-4-sulfonic acid In toluene Reflux;	59%
With toluene-4-sulfonic acid In toluene for 18h; Reflux; Inert atmosphere;

2-bromo-5-chlorobenzaldehyde (174265-12-4) + trimethyleneglycol (504-63-2) → 2-(2-bromo-5-chlorophenyl)-1,3-dioxane

Conditions	Yield
With toluene-4-sulfonic acid In toluene Reflux;	97%

2-bromo-5-chlorobenzaldehyde (174265-12-4) + (methoxymethyl)triphenylphosphonium chloride (4009-98-7) → 1-bromo-4-chloro-2-(2-methoxyvinyl)benzene

Conditions	Yield
Stage #1: (methoxymethyl)triphenylphosphonium chloride With potassium tert-butylate In tetrahydrofuran at -25℃; Inert atmosphere; Stage #2: 2-bromo-5-chlorobenzaldehyde In tetrahydrofuran at -25℃; for 2h; Temperature;	97%
Stage #1: (methoxymethyl)triphenylphosphonium chloride With potassium hexamethylsilazane In toluene at 0 - 20℃; for 1h; Inert atmosphere; Stage #2: 2-bromo-5-chlorobenzaldehyde In toluene at 0 - 20℃; for 7h; Inert atmosphere;
Stage #1: (methoxymethyl)triphenylphosphonium chloride With potassium tert-butylate In tetrahydrofuran at 0 - 20℃; for 0.5h; Inert atmosphere; Stage #2: 2-bromo-5-chlorobenzaldehyde In tetrahydrofuran at 20℃; for 3h; Wittig reaction; Inert atmosphere;
Stage #1: (methoxymethyl)triphenylphosphonium chloride With potassium tert-butylate In tetrahydrofuran at 0℃; for 0.5h; Inert atmosphere; Stage #2: 2-bromo-5-chlorobenzaldehyde In tetrahydrofuran at 0 - 24℃; for 24.5h; Inert atmosphere;

2-bromo-5-chlorobenzaldehyde (174265-12-4) + 2-(2-hydroxy-3-methoxyphenyl)acetonitrile (42973-56-8) → 2-chloro-6-methoxydibenzo[b,f]oxepine-10-carbonitrile (1446201-58-6)

Conditions	Yield
With copper(l) iodide; caesium carbonate In N,N-dimethyl-formamide at 100℃; Inert atmosphere;	97%

2-bromo-5-chlorobenzaldehyde (174265-12-4) + 4-chloro-aniline (106-47-8) → 2,7-dichloroacridine

Conditions	Yield
Stage #1: 4-chloro-aniline With 1,1'-bis-(diphenylphosphino)ferrocene; tris-(dibenzylideneacetone)dipalladium(0); potassium carbonate In toluene at 20℃; for 0.0833333h; Inert atmosphere; Stage #2: 2-bromo-5-chlorobenzaldehyde In toluene at 80℃; for 12h; Inert atmosphere; Stage #3: With aluminum (III) chloride In toluene at 80℃; for 12h;	97%

2-bromo-5-chlorobenzaldehyde (174265-12-4) + tert-butylamine (75-64-9) → (E)-N-(2-bromo-5-chlorobenzylidene)-2-methylpropan-2-amine

Conditions	Yield
at 80℃; for 17h; Sealed tube;	97%

2-bromo-5-chlorobenzaldehyde (174265-12-4) + 2,4-difluorophenylboronic acid (144025-03-6) → 4-chloro-2',4'-difluoro-[1,1'-biphenyl]-2-carbaldehyde

Conditions	Yield
With potassium phosphate monohydrate; C66H84O10P2Pd In water; toluene at 45℃; for 3h; Reagent/catalyst; Solvent; Suzuki-Miyaura Coupling; Inert atmosphere;	97%
With potassium phosphate monohydrate; C50H64NO6PPdS In water at 45℃; for 3h; Suzuki-Miyaura Coupling; Inert atmosphere; Sealed tube;

2-bromo-5-chlorobenzaldehyde (174265-12-4) + (methoxymethyl)triphenylphosphonium chloride (4009-98-7) → 1-bromo-4-chloro-2-(2-methoxyvinyl)benzene

Conditions	Yield
With potassium tert-butylate In Petroleum ether	97%

2-bromo-5-chlorobenzaldehyde (174265-12-4) + phenylboronic acid (98-80-6) → 4-chloro-[1,1'-biphenyl]-2-carbaldehyde (1198208-10-4)

Conditions	Yield
With C35H47O3P*C15H16N(1-)*CH3O3S(1-)*Pd(2+); triethylamine In water at 45℃; for 24h; Suzuki-Miyaura Coupling;	96%
Stage #1: 2-bromo-5-chlorobenzaldehyde; phenylboronic acid With sodium carbonate In water; N,N-dimethyl-formamide for 0.0833333h; Stage #2: With palladium diacetate In water; N,N-dimethyl-formamide at 20℃;	91%
With C64H118O20; C54H72NO6PPdS; triethylamine In tetrahydrofuran; water at 45℃; for 24h; Suzuki-Miyaura Coupling; Inert atmosphere;	90%

2-bromo-5-chlorobenzaldehyde (174265-12-4) + 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (72824-04-5) → (1R)-6-chloro-2,3-dihydro-3-(methylene)inden-1-ol + (1S)-6-chloro-2,3-dihydro-3-(methylene)inden-1-ol

Conditions	Yield
Stage #1: 2-bromo-5-chlorobenzaldehyde; 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane With (R)-3,3′-bis(2,4,6-triisopropylphenyl)-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate; potassium carbonate In water; toluene at -50 - 20℃; for 24h; Stage #2: With bis-triphenylphosphine-palladium(II) chloride; hydrazine hydrate In water; toluene at 100℃; for 20h; enantioselective reaction;	A 96% B n/a

2-bromo-5-chlorobenzaldehyde (174265-12-4) + methylmagnesium bromide (75-16-1) → 1-(2′-bromo-5′-chlorophenyl)ethan-1-ol

Conditions	Yield
In diethyl ether; dibutyl ether at -78 - 0℃; Inert atmosphere;	96%
In tetrahydrofuran at 0℃; Inert atmosphere;	83%
In tetrahydrofuran at 0 - 20℃; for 16h; Inert atmosphere;	81%

2-bromo-5-chlorobenzaldehyde (174265-12-4) + (S)-2-methylpropane-2-sulfinamide (343338-28-3) → S-N-(2-bromo-5-chlorobenzylidene)-2-methylpropane-2-sulfinamide

Conditions	Yield
With caesium carbonate In toluene at 40℃; for 2h; Temperature; Concentration; Solvent;	95.2%
With caesium carbonate In dichloromethane Reflux;

2-bromo-5-chlorobenzaldehyde (174265-12-4) + 2-hydroxybenzyl cyanide (14714-50-2) → 2-chlorodibenzo[b,f]oxepine-10-carbonitrile (1400574-15-3)

Conditions	Yield
With copper(l) iodide; caesium carbonate In N,N-dimethyl-formamide at 100℃; Inert atmosphere;	95%
With caesium carbonate In toluene at 130℃; for 24h; Inert atmosphere; Molecular sieve;	93%

2-bromo-5-chlorobenzaldehyde (174265-12-4) → 1-(2-bromo-5-chlorophenyl)methanamine (942400-60-4)

Conditions	Yield
Stage #1: 2-bromo-5-chlorobenzaldehyde With hydroxylamine In methanol at 20℃; for 4h; Stage #2: With acetic acid; zinc	95%

2-bromo-5-chlorobenzaldehyde (174265-12-4) + 2-(methylamino)-N’-phenylbenzohydrazide → 2-(2-bromo-5-chlorophenyl)-1-methyl-3-(phenylamino)-2,3-dihydroquinazolin-4(1H)-one (1437780-46-5)

Conditions	Yield
With caesium carbonate; copper(I) bromide In 1,4-dioxane for 3h; Reflux;	95%

2-bromo-5-chlorobenzaldehyde (174265-12-4) + carbon monoxide (201230-82-2) → 3-hydroxy-5-chloroisobenzofuran-1(3H)-one (70097-46-0)

Conditions	Yield
With water; palladium diacetate; triethylamine; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene In tetrahydrofuran at 65℃; for 2h; Inert atmosphere;	95%

2-bromo-5-chlorobenzaldehyde (174265-12-4) + 4-dibenzofurylboronic acid (100124-06-9) → C19H11ClO2

Conditions	Yield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In water; toluene for 12h; Reflux; Inert atmosphere;	93%
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In water; toluene for 12h; Inert atmosphere; Reflux;	93%
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In tetrahydrofuran; water for 24h; Reflux; Inert atmosphere;	77%

2-bromo-5-chlorobenzaldehyde (174265-12-4) + phenylvinylboronic acid (14900-39-1) → 5-chloro-2-(1-phenylvinyl)benzaldehyde

Conditions	Yield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In ethanol; water; toluene for 24h; Suzuki-Miyaura Coupling; Inert atmosphere; Reflux;	93%

2-bromo-5-chlorobenzaldehyde (174265-12-4) + 2-(5-bromo-2-hydroxyphenyl)acetonitrile (1261815-96-6) → 8-bromo-2-chlorodibenzo[b,f]oxepine-10-carbonitrile (1446201-66-6)

Conditions	Yield
With copper(l) iodide; caesium carbonate In N,N-dimethyl-formamide at 100℃; Inert atmosphere;	92%

2-bromo-5-chlorobenzaldehyde (174265-12-4) + 2-amino-N'-phenylbenzohydrazide (30086-49-8) → 2-chloro-5-phenylindazolo[3,2-b]quinazolin-7(5H)-one (1437780-33-0)

Conditions	Yield
With caesium carbonate; copper(I) bromide In 1,4-dioxane for 15h; Reflux;	92%
Multi-step reaction with 2 steps 1: citric acid / ethanol / Reflux 2: copper(l) chloride; L-proline; caesium carbonate / dimethyl sulfoxide / 12 h / 90 °C / Inert atmosphere; Schlenk technique View Scheme

Upstream product

• 13780-71-7 dihydroxyborane 
• 7775-19-1 sodium metaborate 
• 587-04-2 m-Chlorobenzaldehyde 
• 33499-36-4 3-chlorobenzaldehyde O-methyloxime 
• 60666-70-8 2-bromo-5-chlorobenzyl alcohol 
• 21739-93-5 2-bromo-5-chlorobenzoic acid 
• 14495-51-3 2-bromo-5-chlorotoluene 
• 1313762-49-0 1-bromo-4-chloro-2-dibromomethylbenzene 
• 882772-93-2 (2-bromo-5-chlorophenyl)methanediyl diacetate 
• 1333-82-0 chromium(VI) oxide 
• 66192-24-3 2-bromo-5-chlorobenzyl bromide 

Downstream Products

• 761425-04-1 1-benzothiophen-2-yl-(5-bromo-2-chlorophenyl)methanol 
• 4792-67-0 5-chloro-indole-2-carboxylic acid ethyl ester 
• 936098-12-3 (E)-methyl 3-(4-chloro-2-formylphenyl)acrylate 
• 1298062-89-1 C₁₁H₉ClO₂ 
• 14548-38-0 6-chloro-1-indanone 
• 1313762-44-5 2-vinyl-5-chlorobenzaldehyde 
• 1308314-50-2 (-)-2-(2-(2-((2R,4S)-2-(tert-butyldiphenylsilyloxy)ethyl)-4-(triisopropylsilyloxy)-3,4-dihydro-2H-pyran-6-yl)-5-chlorophenyl)ethanol 
• 1308314-56-8 (-)-3-(2-((2R,4S)-2-(2-(tert-butyldiphenylsilyloxy)ethyl)-4-(triisopropylsilyloxy)-3,4-dihydro-2H-pyran-6-yl)-5-chlorophenyl)propan-1-ol 
• 1308314-68-2 C₄₁H₅₉ClO₅Si₂ 
• 1308314-90-0 (+)-(1S,3'R,4'S_.6'R)-6'-(2-(tert-butyldiphenylsilyloxy)ethyl)-6-chloro-4'-(triisopropylsilyloxy)-3',4',5',6'-tetrahydrospiro[isochroman-1,2'-pyran]-3'-ol 
• 1308314-66-0 (+)-(1R,3'R,4'S_.6'R)-6'-(2-(tert-butyldiphenylsilyloxy)ethyl)-6-chloro-4'-(triisopropylsilyloxy)-3',4',5',6'-tetrahydrospiro[isochroman-1,2'-pyran]-3'-ol 
• 1308314-91-1 (+)-(1S,3'R,4'S_.6'R)-6'-(2-(tert-butyldiphenylsilyloxy)ethyl)-7-chloro-4'-(triisopropylsilyloxy)-3',4',5',6'-tetrahydro-3H-spiro[benzo[c]oxepine-1,2'-pyran]-3'-ol 
• 265107-67-3 (2-bromo-5-chlorophenyl)acetaldehyde 
• 947614-94-0 2-(2-bromo-5-chloro-phenyl)ethanol 

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