17496-08-1Relevant articles and documents
PROCESS FOR PREPARING CONCENTRATED SOLUTIONS OF SALTS OF ORGANIC ACIDS
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Page/Page column 5, (2009/04/24)
The present invention generally relates to the partial chemical neutralization of organic acids to make compositions used in animal nutrition. More particularly, the present invention relates to the use of a cooled reactor to prepare aqueous compositions of partially neutralized organic acids by a continuous or semi-continuous method of reacting an alkali with an organic acid dispersed or dissolved in an aqueous system. The alkali source is present in an amount less than the stiochometric amount required for complete neutralization of the organic acid.
METHOD FOR PRODUCING ORGANIC ACID
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Page/Page column 23-24, (2008/06/13)
A novel method is provided whereby a free organic acid can be produced particularly from an ammonium salt of an organic acid having a high melting point obtainable by bioconversion of a carbon source in the presence of a neutralizing agent, efficiently at a low cost, and the used material for reaction and a byproduct can be recycled for reuse without being disposed. An ammonium salt of organic acid A such as a dicarboxylic acid, a tricarboxylic acid or an amino acid is subjected to reactive crystallization by means of acid B such as a monocarboxylic acid satisfying the following formula (1), to separate free organic acid A in solid form:pKa(A) ≦ pKa(B) where pKa(A) and pKa(B) represent ionization indices of organic acid A and acid B, respectively, provided that when they have plural values, they represent the minimum pKa among them. The crystallization mother liquor after precipitating and separating organic acid A is, after separating acid B and then an ammonium salt of acid B, recycled for use in the reactive crystallization step. The ammonium salt of acid B is decomposed into acid B and ammonia, which are recycled for use in the reactive crystallization step and as a neutralizing agent in the bioconversion step, respectively.