1785-52-0 Usage
Description
6,11-Dihydroxy-5,12-naphthacenedione is an organic compound with the molecular formula C14H8O4. It is a crystalline solid that has been identified as an impurity in the crystallographic analysis of its structure. 6,11-DIHYDROXY-5,12-NAPHTHACENEDIONE serves as a key intermediate in the synthesis of various complex organic molecules and has potential applications in the fields of chemistry and materials science.
Uses
Used in Chemical Synthesis:
6,11-Dihydroxy-5,12-naphthacenedione is used as a synthetic intermediate for the production of tetracene derivatives, such as 5,6,11,12-tetrachlorotetracene. It is also utilized in the synthesis of (3Z,3′Z)-3,3′-(ethane-1,2-diylidene)bis[isobenzofuran-1(3H)-one], which is an important compound in the field of organic chemistry.
Used in Supramolecular Chemistry:
In the field of supramolecular chemistry, 6,11-dihydroxy-5,12-naphthacenedione is used as a ligand for the synthesis of supramolecular coordination complexes (SCCs). These complexes have potential applications in various areas, including catalysis, sensing, and molecular recognition.
Used in Organometallic Chemistry:
6,11-Dihydroxy-5,12-naphthacenedione is employed in the synthesis of half-sandwich Ir, Rh-based organometallic molecular boxes. These organometallic complexes are of interest due to their unique structures and potential applications in catalysis and materials science.
Used in Self-Assembled Systems:
6,11-DIHYDROXY-5,12-NAPHTHACENEDIONE is also used in the synthesis of self-assembled, chair-shaped dirhenium(I) macrocyclic compounds. Self-assembled systems are of great interest in the field of nanotechnology and materials science, as they can form complex structures with unique properties and potential applications in various fields, such as drug delivery, sensing, and energy storage.
Check Digit Verification of cas no
The CAS Registry Mumber 1785-52-0 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 1,7,8 and 5 respectively; the second part has 2 digits, 5 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 1785-52:
(6*1)+(5*7)+(4*8)+(3*5)+(2*5)+(1*2)=100
100 % 10 = 0
So 1785-52-0 is a valid CAS Registry Number.
InChI:InChI=1/C18H10O4/c19-15-9-5-1-2-6-10(9)16(20)14-13(15)17(21)11-7-3-4-8-12(11)18(14)22/h1-8,19-20H
1785-52-0Relevant articles and documents
Synthesis, Rearrangement, and Hauser Annulation of 3-Isocyanophthalides
Mal, Dipakranjan,Ghosh, Ketaki,Chakraborty, Soumen
, p. 2473 - 2484 (2015/08/18)
3-Isocyanoisobenzofuran-1(3H)-ones (phthalides) were prepared in two steps from the corresponding phthalaldehydic acids. The 3-isocyanoisobenzofuran-1(3H)-ones are readily rearranged to the corresponding 3-cyanoisobenzofuran-1(3H)-ones using triflic anhyd
Direct access to 1,4-dihydroxyanthraquinones: The Hauser annulation reexamined with p-quinones
Mal, Dipakranjan,Ray, Sutapa,Sharma, Indrajeet
, p. 4981 - 4984 (2008/02/05)
(Chemical Equation Presented) 3-Phenylsulfanylphthalides (e.g. 8a) readily react with p-benzoquinones in the presence of LiOtBu in THF to furnish 1,4-dihydroxyanthraquinones in good yields and one-pot operations.
METAL TEMPLATE ORTHO-ACYLATION OF PHENOLS; A NEW GENERAL APPROACH TO ANTHRACYCLINONES
Sartori, Giovanni,Casnati, Giuseppe,Bigi, Franca,Robles, Pasquale
, p. 1533 - 1536 (2007/10/02)
Direct and mild synthesis of dihydroxyanthraquinones including 4-demethoxy-7-deoxydaunomycinone 8 from ortho-phthaloyl dichloride and hydroquinone derivatives is described.
