18000-76-5Relevant articles and documents
Dehydrogenation of Cyanamides. An Approach to Cyanimides and Carbonyl Compounds
Carrau, Reyes,Freire, Raimundo,Hernandez, Rosendo,Suarez, Ernesto
, p. 1055 - 1058 (1986)
Treatment of cyanamides with lead tetraacetate afforded the corresponding cyanimides in high yields.As these compounds can be readily and efficiently hydrolysed to carbonyl compounds; this sequence of reactions allows the synthesis of aldehydes and ketones from primary amines.
Synthesis of 17-(isocyanotosylmethylene) steroids: precursors to pregnane derivatives
Leusen, Daan van,Leusen, Albert M. van
, p. 393 - 401 (2007/10/02)
The synthesis is described of a series of twenty 17-(isocyanotosylmethylene) steroids 5 from 17-oxo steroids and 4-tolylsulfonylmethyl isocyanide (TosMIC).Furthermore, nine analogous 17-(isocyanosulfonylmethylene) steroids (15-21a) have been prepared usin
INFRARED SPECTRA OF COMPOUNDS WITH THE METHOXYMETHYL PROTECTING GROUP
Vasickova, Sona,Pouzar, Vladimir,Cerny, Ivan,Drasar, Pavel
, p. 90 - 100 (2007/10/02)
Infrared spectra of a series of compounds containing the CH3OCH2O- (MOM-O-) group have been studied.All the spectra exhibit three characteristic strong absorbtion bands due to coupled stretching vibrations of C-O-C-O-C grouping in the region 1200 - 1000 c