187874-76-6

Basic information

• Product Name: ((Z)-1-Bromo-2-phenyl-vinyl)-bis-(1,2-dimethyl-propyl)-borane
• CAS NO: 187874-76-6
• Molecular Weight: 335.135
• Mol File: 187874-76-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: ((Z)-1-Bromo-2-phenyl-vinyl)-bis-(1,2-dimethyl-propyl)-borane(CAS DataBase Reference)
• NIST Chemistry Reference: ((Z)-1-Bromo-2-phenyl-vinyl)-bis-(1,2-dimethyl-propyl)-borane(187874-76-6)
• EPA Substance Registry System: ((Z)-1-Bromo-2-phenyl-vinyl)-bis-(1,2-dimethyl-propyl)-borane(187874-76-6)

Safety Data

• Hazardous Substances Data: 187874-76-6(Hazardous Substances Data)

Upstream product

• 932-87-6 1-Bromo-2-phenylacetylene 

Downstream Products

• 97632-25-2 (Z)-penta-1,4-dien-1-ylbenzene 
• 42599-24-6 E-styryl iodide 
• 57918-63-5 (Z)-styryl iodide 
• 187875-16-7 (Z)-2-phenylethenyldisiamylborane 

Relevant articles and documents

Stereoselective dehalogenation of (Z)-1-halo-1-alkenyldialkylborane with tributyltin hydride: The behavior of tributyltin hydride as a hydride donor

The reaction of (Z)-1-halo-1-alkenyldialkylborane (1) with tributyltin hydride (n-Bu3SnH) at 0°C or room temperature results in reductive removal of the halogen atom to afford (E)- or (Z)-1-alkenyldialkylborane whose stereochemistry depends on the dialkylboryl group and the alkenyl group of 1.