189125-29-9

Basic information

• Product Name: 3-Cyclohexene-1-carboxylicacid,6-amino-,(1R,6S)-(9CI)
• Synonyms: 3-Cyclohexene-1-carboxylicacid,6-amino-,(1R,6S)-(9CI)
• CAS NO: 189125-29-9
• Molecular Formula: C₇H₁₁NO₂
• Molecular Weight: 141.17
• Product Categories: AMINOACID
• Mol File: 189125-29-9.mol
• Article Data: 9

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 3-Cyclohexene-1-carboxylicacid,6-amino-,(1R,6S)-(9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Cyclohexene-1-carboxylicacid,6-amino-,(1R,6S)-(9CI)(189125-29-9)
• EPA Substance Registry System: 3-Cyclohexene-1-carboxylicacid,6-amino-,(1R,6S)-(9CI)(189125-29-9)

Safety Data

• Hazardous Substances Data: 189125-29-9(Hazardous Substances Data)

Upstream product

• 20205-48-5 8-oxo-7-azabicyclo<4.2.0>oct-2-ene 
• 20205-48-5 7-azabicyclo<4.2.0>oct-3-en-8-one 
• 28907-18-8 (1S,2R)-Cyclohex-4-ene-1,2-dicarboxylic acid diamide 
• 285560-91-0 Butyric acid (1R,6S)-8-oxo-7-aza-bicyclo[4.2.0]oct-3-en-7-ylmethyl ester 
• 1469-48-3 cis-1,2,3,6-Tetrahydrophthalimide 
• 1165952-91-9 cyclohexa-1,3-diene 

Downstream Products

• 191803-49-3 C₇H₁₃NO 
• 1334880-63-5 ethyl (1S,2S,5S)-2-(tert-butoxycarbonylamino)-5-fluorocyclohexanecarboxylate 
• 1334880-58-8 ethyl (1R,2S,5S)-2-(tert-butoxycarbonylamino)-5-fluorocyclohexanecarboxylate 
• 1334880-56-6 ethyl (1R,2S,5R)-2-(tert-Butoxycarbonylamino)-5-hydroxycyclohexanecarboxylate 
• 1228187-00-5 ethyl (1S,2S,5R)-2-(tert-butoxycarbonylamino)-5-hydroxycyclohexanecarboxylate 
• 1228186-99-9 ethyl (1S,2S,5S)-2-(tert-butoxycarbonylamino)-5-hydroxycyclohex-3-enecarboxylate 
• 1228186-98-8 ethyl (1R,2S,5S)-2-(tert-butoxycarbonylamino)-5-hydroxycyclohex-3-enecarboxylate 
• 1226812-49-2 (1R,6S)-6-(tert-butoxycarbonylamino)cyclohex-3-enecarboxylic acid 
• 1036760-05-0 ethyl (1R,2S)-2-(benzyloxycarbonylamino)-4-cyclohexenecarboxylate 

Relevant articles and documents

Modification of the Enantioselectivity of Biocatalytic meso-Desymmetrization for Synthesis of Both Enantiomers of cis-1,2-Disubstituted Cyclohexane by Amidase Engineering

Both enantiomers of cis-1,2-disubstituted cyclohexane have been obtained enantioselectively through engineered amidase-catalyzed desymmetrization of meso carbocyclic 1,2-dicarboxamides under mild condition. Based on the enzyme-substrate binding model sugg

Cis-2-Aminocyclohex-4-enecarboxylic acid as a new building block of helical foldamers

cis-2-Aminocyclohex-4-enecarboxylic acid (cis-ACHE) is a conformationally constrained β-amino acid. We showed that the conformational preference of a cis-ACHE residue is similar to that of cis-2-aminocyclohexanecarboxylic acid. α/β-Peptides that consist o

Enantiomeric discrimination of cyclic β-amino acids using (18-crown-6)-2,3,11,12-tetracarboxylic acid as a chiral NMR solvating agent

(18-Crown-6)-2,3,11,12-tetracarboxylic acid is an excellent chiral NMR solvating agent for cyclic β-amino acids with cyclopentane, cyclohexane, cycloheptane, cyclopentene, cyclohexene, bicyclo[2.2.1]heptane, and bicyclo[2.2.1]heptene rings. The crown ether was added to the neutral β-amino acids in methanol-d4. A neutralization reaction between the crown ether and β-amino acid forms the ammonium ion needed for favorable association. Enantiomeric discrimination of the two hydrogen atoms α to the amine and carboxylic acid moieties of the β-amino acid was observed with every substrate studied. Trends in the order of the enantiomeric discrimination of certain hydrogen atoms for substrates of similar structures correlate with the absolute configuration.