19360-96-4

Basic information

• Product Name: 4-(benzylsulfanyl)butan-2-one
• CAS NO: 19360-96-4
• Molecular Formula: C₁₁H₁₄OS
• Molecular Weight: 194.2933
• Mol File: 19360-96-4.mol
• Article Data: 30

Chemical Properties

• Boiling Point: 305.7°C at 760 mmHg
• Flash Point: 149.5°C
• Density: 1.062g/cm³
• Vapor Pressure: 0.00081mmHg at 25°C
• Refractive Index: 1.544
• CAS DataBase Reference: 4-(benzylsulfanyl)butan-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: 4-(benzylsulfanyl)butan-2-one(19360-96-4)
• EPA Substance Registry System: 4-(benzylsulfanyl)butan-2-one(19360-96-4)

Safety Data

• Hazardous Substances Data: 19360-96-4(Hazardous Substances Data)

Upstream product

• 78-94-4 methyl vinyl ketone 
• 100-53-8 phenylmethanethiol 
• 100-44-7 benzyl chloride 
• 100-39-0 benzyl bromide 
• 123-91-1 1,4-dioxane 
• 7732-18-5 water 
• 100-85-6 N-benzyl-trimethylammonium hydroxide 
• 150-60-7 dibenzyl disulphide 
• 75908-55-3 3-(benzylthio)-1,2-benzisothiazole 1,1-dioxide 

Downstream Products

• 92730-56-8 β-Hydroxy-β-methyl-δ-benzylmercapto-valeriansaeure-ethylester 
• 1170669-07-4 N₂-acetyl-N₁,N₂-dibenzyl-4-(benzylthio)isovalinamide 
• 1170669-31-4 ethyl N-{(4S)-4-(benzyloxycarbonyl)-4-[(tert-butoxycarbonyl)amino]butanoyl}-N-benzyl-4-(benzylthio)isovalyl-β-alaninate 
• 1170669-16-5 ethyl 1-benzyl-5-[2-(benzylthio)ethyl]-5-methyl-4,5-dihydro-1H-imidazole-4-carboxylate 
• 1170669-12-1 ethyl N-acetyl-N-benzyl-4-(benzylthio)isovalylglycinate 
• 1170669-21-2 ethyl N-{(4S)-4-(methyloxycarbonyl)-4-[(tert-butoxycarbonyl)amino]butanoyl}-N-benzyl-4-(benzylthio)isovalylglycinate 
• 1170669-28-9 benzyl (2S)-5-{benzyl[3-(benzylthio)-1-methyl-1-{[(4-methyl-2,6,7-trioxabicyclo[2.2.2]oct-1-yl)methyl]carbamoyl}propyl]amino}-2-[(tert-butoxycarbonyl)amino]-5-oxopentanoate 
• 92157-08-9 β-Hydroxy-β-methyl-δ-benzylmercapto-valeriansaeure 
• 72648-21-6 5-<3-(thioethyl)benzyl>-5-methylhydantoin 
• 88738-53-8 4-[(phenylmethyl)sulfinyl]-2-butanone 

Relevant articles and documents

Ceric ammonium nitrate (CAN) as a green and highly efficient promoter for the 1,4-addition of thiols and benzeneselenol to α,β-unsaturated ketones

A mild and efficient process for the 1,4-addition of thiols and benzeneselenols to various α,β-unsaturated ketones using a catalytic amount of CAN with excellent product yields is described. This inexpensive, nontoxic, and readily available catalytic ceric(IV) ammonium nitrate system efficiently catalyzes conjugate addition reactions between thiol derivatives and various α,β-unsaturated ketones under solvent-free conditions. A plausible mechanism for the role of CAN, both as a promoter in free radical chain addition reactions as well as a catalyst for the conjugate addition process is proposed.

To Coordinate or not to Coordinate: The Special Role of Chalcogen Ether Functionalities in the Design of Twofold Functionalized Cyclopentadienyl Ligands [Cp,O,Ch (Ch = S, Se)]

The solvent- and catalyst free synthesis of two β-thio ketones L1a and L1b is reported. L1a, L1b, and a β-seleno ketone L1c were successfully employed as ligand precursors in the synthesis of a novel series of cationic titanium complexes 4a–4c via a well-

Photo-biocatalytic One-Pot Cascades for the Enantioselective Synthesis of 1,3-Mercaptoalkanol Volatile Sulfur Compounds

The synthesis of enantiomerically pure 1,3-mercaptoalkanol volatile sulfur compounds through a one-pot photo-biocatalytic cascade reaction is described. Two new KRED biocatalysts with opposite enantioselectivity were discovered and proved to be efficient

Mild hydrosulfenylation of Olefins under neutral conditions using a defined NHC-ligated iron-sulfur catalyst

A defined NHC-Fe-S complex proved to be an efficient catalyst for the selective hydrosulfenylation of α,β-unsaturated ketones or vinylnitriles. A wide range of different aliphatic thiols were transferred in this atom-economic reaction into the correspondi