199123-01-8

Basic information

• Product Name: 2-(4-Chloro-2-nitro-phenyl)-ethanesulfonic acid (2R,3S,5R)-3-hydroxy-5-{4-[2-(4-nitro-phenyl)-ethoxycarbonylamino]-2-oxo-2H-pyrimidin-1-yl}-tetrahydro-furan-2-ylmethyl ester
• CAS NO: 199123-01-8
• Molecular Weight: 668.038
• Mol File: 199123-01-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-(4-Chloro-2-nitro-phenyl)-ethanesulfonic acid (2R,3S,5R)-3-hydroxy-5-{4-[2-(4-nitro-phenyl)-ethoxycarbonylamino]-2-oxo-2H-pyrimidin-1-yl}-tetrahydro-furan-2-ylmethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(4-Chloro-2-nitro-phenyl)-ethanesulfonic acid (2R,3S,5R)-3-hydroxy-5-{4-[2-(4-nitro-phenyl)-ethoxycarbonylamino]-2-oxo-2H-pyrimidin-1-yl}-tetrahydro-furan-2-ylmethyl ester(199123-01-8)
• EPA Substance Registry System: 2-(4-Chloro-2-nitro-phenyl)-ethanesulfonic acid (2R,3S,5R)-3-hydroxy-5-{4-[2-(4-nitro-phenyl)-ethoxycarbonylamino]-2-oxo-2H-pyrimidin-1-yl}-tetrahydro-furan-2-ylmethyl ester(199123-01-8)

Safety Data

• Hazardous Substances Data: 199123-01-8(Hazardous Substances Data)

Upstream product

• 52536-97-7 4-chloro-1-(2-chloroethyl)-2-nitro-benzene 
• 16764-17-3 2-(4-chloro-2-nitrophenyl)ethan-1-ol 
• 89-59-8 4-chloro-2-nitrotoluene 
• 88091-67-2 2'-deoxy-N⁴-{[2-(4-nitrophenyl)ethoxy]carbonyl}cytidine 
• 199122-95-7 2-(4-chloro-2-nitrophenyl)ethylsulfonyl chloride 

Relevant articles and documents

New photolabile protecting groups in nucleoside and nucleotide chemistry - Synthesis, cleavage mechanisms and applications

New photolabile protecting groups have been found in the 2-(2- nitrophenyl)ethoxycarbonyl and the 2-(2-nitrophenyl)ethylsulfonyl group, respectively. The influence of substituents at the phenyl ring as well as the side-chain has been investigated regarding the photolysis rates on irradiation at 365 mn. β-Branching in the side-chain leads to highly increased rates of photodeprotection. A new type of photocleavage mechanism consisting of a photoinduced β-elimination process is proposed.