201486-97-7

Basic information

• Product Name: 2-fluoro-1-(3-iodopropyl)benzene
• Synonyms: 2-fluoro-1-(3-iodopropyl)benzene
• CAS NO: 201486-97-7
• Molecular Weight: 264.081
• Mol File: 201486-97-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 2-fluoro-1-(3-iodopropyl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 2-fluoro-1-(3-iodopropyl)benzene(201486-97-7)
• EPA Substance Registry System: 2-fluoro-1-(3-iodopropyl)benzene(201486-97-7)

Safety Data

• Hazardous Substances Data: 201486-97-7(Hazardous Substances Data)

Upstream product

• 446-52-6 2-Fluorobenzaldehyde 
• 76727-24-7 3-(2-fluorophenyl)propan-1-ol 
• 1643-26-1 3-(2-fluorophenyl)propionic acid 
• 166949-93-5 1-[3-(methylsulfonyloxy)propyl]-2-fluorobenzene 
• 18944-77-9 2-fluorocinnamic acid 

Downstream Products

• 496-11-7 INDANE 
• 6134-53-8 4-bromo-2,3-dihydro-1H-indene 
• 912551-99-6 1-fluoro-2-propylbenzene 
• 201486-99-9 (+/-)-Hydroxy-phenyl-(indanyl-⁽⁴⁾)-methan 

Relevant articles and documents

Site-Selective C(sp3)–H Functionalization of Fluorinated Alkanes Driven by Polar Effects Using a Tungstate Photocatalyst

The TBADT-catalyzed C(sp3)–H functionalization of perfluorophenyl- and perfluoroalkyl-substituted alkanes was studied to determine how the fluorous substituents affect site-selectivity. Alkylation of alkyl-substituted perfluorobenzene avoids α-C–H bonds, unlike their alkylbenzene counterparts, allowing site-selective functionalization of C–H bonds remote to the aromatic ring. Alkylation of alkanes having a perfluoroalkyl group also avoided α-C–H bonds. Radical polar effects in the SH2 transition states could explain this avoidance of α-C–H functionalization.