202289-10-9

Basic information

• Product Name: RuCl₂(1,3-bis(diphenylphosphanyl)propane)2
• CAS NO: 202289-10-9
• Molecular Weight: 996.878
• Mol File: 202289-10-9.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: RuCl₂(1,3-bis(diphenylphosphanyl)propane)2(CAS DataBase Reference)
• NIST Chemistry Reference: RuCl₂(1,3-bis(diphenylphosphanyl)propane)2(202289-10-9)
• EPA Substance Registry System: RuCl₂(1,3-bis(diphenylphosphanyl)propane)2(202289-10-9)

Safety Data

• Hazardous Substances Data: 202289-10-9(Hazardous Substances Data)

Upstream product

• 15529-49-4 tris(triphenylphosphine)ruthenium(II) chloride 
• 6737-42-4 1,3-bis-(diphenylphosphino)propane 

Downstream Products

• 20427-56-9 ruthenium tetroxide 
• 55669-31-3 [RuCl(1,3-bis(diphenylphosphino)propane)2][PF₆] 
• 1299494-45-3 trans-Cl₂Ru(1,3-bis(diphenylphosphino)propane)(C₆H₁₀(NH₂)2) 
• 531498-69-8 trans-Cl₂Ru(1,3-bis(diphenylphosphino)propane)(C₆H₃(NH₂)2CH₃) 
• 531498-68-7 trans-Cl₂Ru(1,3-bis(diphenylphosphino)propane)(C₆H₄(NH₂)2) 
• 531498-72-3 trans-Cl₂Ru(1,3-bis(diphenylphosphino)propane)(H₂NCH₂C(CH₃)2CH₂NH₂) 
• 12137-44-9 ruthenium (II) oxide 
• 531498-74-5 trans-Cl₂Ru(1,3-bis(diphenylphosphino)propane)(H₂NCH(CH₂CH₃)CH₂CH₂NH₂) 
• 531498-76-7 trans-Cl₂Ru(1,3-bis(diphenylphosphino)propane)(H₂NCH₂CH₂CH₂CH₂NH₂) 
• 531498-71-2 trans-Cl₂Ru(1,3-bis(diphenylphosphino)propane)(H₂NCH₂CH₂CH₂NH₂) 
• 151708-55-3 RuCl₂((C₆H₅)2PC₃H₆P(C₆H₅)2)2⁽¹⁺⁾*BF₄^(1-)={RuCl₂((C₆H₅)2PC₃H₆P(C₆H₅)2)2}BF₄ 
• 118444-63-6 RuCl(1,3-bis(diphenylphosphino)propane)2(ClO₄) 
• 531498-66-5 trans-Cl₂Ru(1,3-bis(diphenylphosphino)propane)(H₂NC(CH₃)2CH₂NH₂) 

Relevant articles and documents

Synthesis, structure, spectroscopic properties, electrochemistry, and DFT correlative studies of trans-[Ru(P-P)2Cl2] complexes

Five trans-[Ru(P-P)2Cl2] complexes were prepared by reacting RuCl2(PPh3)3 with P-P ligands {P-P = 3-hexyl-1,3-bis(diphenylphosphino)propane (hdppp) (1); = 1,3- bis(diphenylphosphino)propane (dppp) (2); = 1,2-bis(diphenylphosphino)ethane (dppe) (3); 1.1′-bis(diphenylphosphino)methane (dppm) (4); 1,2-bis(diphenylphosphino)ethylene (depe) (5)}. The complexes were characterized by an elemental analysis, IR, 1H, 13C and 31P{1H}NMR, FAB-MS and TG/DTA. These Ru(II) complexes showed Ru(III)/Ru(II) quasireversible redox couple. The molecular structures of the complexes 1 and 3 were determined by X-ray crystallography, and their spectroscopic properties were studied. Another polymorph of 3 was reported in literature, the reported polymorph of 3 in this work crystallizes in P1 space group, whereas, the previously reported polymorph crystallizes in C2/c space group. The two complexes adopt a distorted trans octahedral coordination and ruthenium(II) ions are located on a crystallographic centre of symmetry. Based on the optimized structures, computational investigations were carried out in order to determine the electronic structures of the complexes. The electronic spectra of 1 and 1+ in dichloromethane were calculated with the use of time-dependent DFT methods, and the electronic spectra of the transitions were correlated with the molecular orbitals of the complexes.

OCTAHEDRAL AND TRIGONAL-BIPYRAMIDAL COMPLEXES OF RUTHENIUM(II) WITH BIDENTATE PHOSPHINE LIGANDS

Six- and five-co-ordinate complexes of ruthenium(II) with the unsymmetrical diphosphine ligand Ph2P(CH2)3PMe2 have been prepared.Phosphorus-31 n.m.r. spectroscopy indicates that octahedral complexes , , and ClO4 (P-P = diphosphine ligand) have the all-trans arrangement with Me2P trans to Me2P and Ph2P trans to Ph2P.The five-co-ordinate complexes BPh4, where X = Cl or H, are not fluxional at room temperature and have a trigonal-bipyramidal structure with axial PMe2 groups and equatorial PPh2 groups.Similar structures are proposed for analogous complexes of Ph2P(CH2)3PMePh and of Ph2P(CH2)3PPh2.