208935-32-4Relevant articles and documents
Stereoselective synthesis of (+)-spectaline
Lee, Yiu-Suk,Shin, Yong-Ho,Kim, Yong-Hyun,Lee, Kee-Young,Oh, Chang-Young,Pyun, Sung-Jae,Park, Hyun-Ju,Jeong, Jin-Hyun,Ham, Won-Hun
, p. 87 - 93 (2007/10/03)
Our synthesis of (+)-spectaline revealed that the methodology involving diastereoselective palladium(0)-catalyzed oxazoline formation and intramolecular reductive amination by catalytic hydrogenation of an oxazoline is an effective method for the asymmetric synthesis of natural products possessing complex functionalized piperidine cores.
Total synthesis of myriocin
Lee, Kee-Young,Oh, Chang-Young,Kim, Yong-Hyun,Joo, Jae-Eun,Ham, Won-Hun
, p. 9361 - 9363 (2007/10/03)
A concise, stereocontrolled synthesis of myriocin was achieved. Key features involve diastereoselective oxazoline formation catalyzed by palladium(0), MgBr2-promoted allylic stannane addition, and palladium(0)-catalyzed coupling of a vinyl iodide with an organozinc reagent.