210880-92-5

Basic information

• Product Name: Clothianidin
• Synonyms: CLOTHIANIDIN;Clothianidin PESTANAL;Guanidine, N-(2-chloro-5-thiazolyl)methyl-N-methyl-N-nitro-, C(E)-;clothianidine;3-[(2-chloro-1,3-thiazol-5-yl)methyl]-2-methyl-1-nitro-guanidine;CLOTHIANIDIN STANDARD;(E)-1-(2-Chloro-1,3-thiazol-5-ylmethyl)-3-methyl-2-nitroguanidine;(E)-1-(2-Chloro-5-thiazolylmethyl)-3-methyl-2-nitroguanidine
• CAS NO: 210880-92-5
• Molecular Formula: C6H8ClN5O2S
• Molecular Weight: 249.68
• Product Categories: NULL;Agrochemical
• Mol File: 210880-92-5.mol
• Article Data: 19

Chemical Properties

• Melting Point: 178.8 °C
• Boiling Point: 435.2°C at 760 mmHg
• Flash Point: 217°C
• Appearance: /
• Density: 1.61
• Vapor Pressure: 8.93E-08mmHg at 25°C
• Refractive Index: 1.709
• Storage Temp.: 0-6°C
• PKA: 2.76±0.50(Predicted)
• Water Solubility: 327 mg/L at 20 ºC
• CAS DataBase Reference: Clothianidin(CAS DataBase Reference)
• NIST Chemistry Reference: Clothianidin(210880-92-5)
• EPA Substance Registry System: Clothianidin(210880-92-5)

Safety Data

• Hazard Codes: Xn,N
• Statements: 22-50/53
• Safety Statements: 46-60-61
• RIDADR: UN 3077 9 / PGIII
• WGK Germany: 1
• RTECS: ME9565000
• Hazardous Substances Data: 210880-92-5(Hazardous Substances Data)

Usage

Uses

Insecticide.

Flammability and Explosibility

Notclassified

InChI:InChI=1/C6H8ClN5O2S/c1-8-6(11-12(13)14)10-3-4-2-9-5(7)15-4/h2H,3H2,1H3,(H2,8,10,11)

Upstream product

• 187149-02-6 O-methyl-N-(2-chloro-5-thiazolylmethyl)-N'-nitroisourea 
• 120740-08-1 [(2-chloro-5-thiazolyl)methyl]amine 
• 136516-19-3 1-[(2-chloro-5-thiazolyl)methyl]tetrahydro-3,5-dimethyl-N-nitro-1,3,5-triazin-2(1H)-imine 
• 57538-27-9 2-methyl-1-nitroisourea 
• 305838-80-6 C₁₀H₁₅ClN₆O₂S 

Relevant articles and documents

Method for preparing clothianidin

The invention discloses a method for preparing clothianidin. The response equation is shown in the description, wherein R is selected from C1-C6 alkyl, benzyl, phenethyl and phenylpropyl; an oxidationreagent is selected from hydrogen peroxide, hydrogen peroxide-oxygen and ozone; a catalyst is selected from sodium hydroxide, potassium hydroxide, formic acid, acetic acid, hydrochloric acid and sulfuric acid. A compound I shown in the response equation is oxidized by the oxidation reagent in suitable solvent under the effect of the catalyst to prepare into the clothianidin. According to the method, the clothianidin is prepared with the method for oxidizing the compound I with the oxidation reagent, the production cost is reduced, reaction conditions are mild, the atom utilization rate is high, brine waste is avoided, and a post-processing method is simple and easy to carry out, economical and effective, and is capable of easily achieving industrial production.

NOXIOUS ARTHROPOD CONTROL AGENT CONTAINING AMIDE COMPOUND

An object of the present invention is to provide a compound having the controlling activity on a noxious arthropod, and a noxious arthropod controlling agent containing an amide compound of formula (I): wherein X represents a nitrogen atom or a CH group, p represents 0 or 1, A represents a tetrahydrofuranyl group or the like, R1, R2, R3, R4, R5, R6 and R7 represent a hydrogen atom or the like, n represents 1 or 2, Y represents an oxygen atom or the like, m represents any integer of 0 to 7, and Q represents a C1-8 chain hydrocarbon group optionally having a phenyl group or the like, has the excellent noxious arthropod controlling effect.

Use of prochloraz for wood protection

The active compound prochloraz and fungicidal compositions based on prochloraz are highly suitable for protecting wood and timber products against attack and/or destruction by soft-rot fungi.