213598-45-9

Basic information

• Product Name: (3aR,6aS)-2,2-dimethyl-4,6a-dihydro-3aH-[1,3]dioxolo[4,5-c]pyrrole-N-oxide
• Synonyms: (3aR,6aS)-2,2-dimethyl-4,6a-dihydro-3aH-[1,3]dioxolo[4,5-c]pyrrole-N-oxide
• CAS NO: 213598-45-9
• Molecular Formula: C₇H₁₁NO₃
• Molecular Weight: 157
• EINECS: -0
• Mol File: 213598-45-9.mol
• Article Data: 11

Chemical Properties

• Appearance: /
• CAS DataBase Reference: (3aR,6aS)-2,2-dimethyl-4,6a-dihydro-3aH-[1,3]dioxolo[4,5-c]pyrrole-N-oxide(CAS DataBase Reference)
• NIST Chemistry Reference: (3aR,6aS)-2,2-dimethyl-4,6a-dihydro-3aH-[1,3]dioxolo[4,5-c]pyrrole-N-oxide(213598-45-9)
• EPA Substance Registry System: (3aR,6aS)-2,2-dimethyl-4,6a-dihydro-3aH-[1,3]dioxolo[4,5-c]pyrrole-N-oxide(213598-45-9)

Safety Data

• Hazardous Substances Data: 213598-45-9(Hazardous Substances Data)

Upstream product

• 152139-64-5 (meso)-3,4-isopropylidenedioxy-2,5-pyrrolidine hydrotosylate 
• 223396-44-9 meso 3,4-cis-isopropylidenedioxy-1-hydroxypyrrolidine 
• 2873-29-2 D-glucal triacetate 
• 189996-60-9 2,3-O-isopropylidene-D-erythrose 
• 33647-85-7 isolevoglucosenone 
• 124-63-0 methanesulfonyl chloride 
• 849480-74-6 (E/Z)-2,3-O-ispropylidene-D-erythrose-oxime 
• 63952-83-0 (2S)-acetic acid 6-oxo-3,6-dihydro-2H-pyran-2-ylmethyl ester 
• 55904-12-6 ((4R,5S)-5-Hydroxymethyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-methanol 
• 38279-61-7 meso-2,3-O-isopropylidene-1,4-di-O-(methanesulfonyl)butane-1,2,3,4-tetrol 
• 151948-15-1 (3aR,6aS)-5-benzyl-2,2-dimethyltetrahydro-3aH-[1,3]dioxolo[4,5-c]pyrrole 

Downstream Products

• 1313032-46-0 C₁₄H₁₇NO₅S 
• 1341196-78-8 (3S,3aS,4S,5R)-3-phenylsulfonyl-3a-phenylsulfonylmethyl-4,5-isopropylidenedioxy-hexahydropyrrolo[1,2-b]isoxazole 
• 1341196-79-9 (2S,3aS,4S,5R)-2-phenylsulfonyl-3a-phenylsulfonylmethyl-4,5-isopropylidenedioxy-hexahydropyrrolo[1,2-b]isoxazole 
• 1341196-80-2 (2R,3aS,4S,5R)-2-phenylsulfonyl-3a-phenylsulfonylmethyl-4,5-isopropylidenedioxy-hexahydropyrrolo[1,2-b]isoxazole 
• 1341196-81-3 (2R,3aR,4S,5R)-2-phenylsulfonyl-3a-phenylsulfonylmethyl-4,5-isopropylidenedioxy-hexahydropyrrolo[1,2-b]isoxazole 
• 1341196-82-4 (2S,3S,4R)-2-(2-hydroxyethyl)-2-phenylsulfonylmethyl-3,4-isopropylidenedioxypyrrolidine 
• 1341196-83-5 (2R,3S,4R)-2-(2-hydroxyethyl)-2-phenylsulfonylmethyl-3,4-isopropylidenedioxypyrrolidine 
• 1446141-89-4 (1′R,3S,4R)-3,4-isopropylidenedioxy-5-[(1′-phenylsulfonyl)(2′-phenyl)ethyl]-3,4-dihydro-2H-pyrrole 1-oxide 
• 1446141-88-3 ( 1′R,2R,3S,4R)-2-[(1′-phenylsulfonyl)(2′-(2-propynyloxytetrahydropirane))ethyl]-1-hydroxy-3,4-isopropylidenedioxypyrrolidine 
• 1446141-87-2 (1′R,2R,3S,4R)-2-[(1′-phenylsulfonyl)(3′-(4-methoxyphenyl))-propyl]-1-hydroxy-3,4-isopropylidenedioxypyrrolidine 
• 1446141-86-1 (1′R,2R,3S,4R)-2-[(1′-phenylsulfonyl)(3′-phenyl)propyl]-1-hydroxy-3,4-isopropylidenedioxypyrrolidine 
• 1446141-85-0 (1′R,2R,3S,4R)-2-[(1′-phenylsulfonyl)(2′-(4-fluorophenyl))ethyl]-1-hydroxy-3,4-isopropylidenedioxypyrrolidine 
• 1446141-84-9 (1′R,2R,3S,4R)-2-[(1′-phenylsulfonyl)(2′-phenyl)ethyl]-1-hydroxy-3,4-isopropylidenedioxypyrrolidine 
• 1446141-83-8 (1′R,2R,3S,4R)-2-[(1′-phenylsulfonyl)(4′-methyl)pent-4′-enyl]-1-hydroxy-3,4-isopropylidenedioxypyrrolidine 

Relevant articles and documents

Oxidation of hydroxylamines to nitrones catalyzed by (salen)Mn(III) complexes. Enantioselective synthesis of a protected cis-dihydroxypyrroline N-oxide with Jacobsen catalyst

Oxidation of N,N-disubstituted hydroxylamines to nitrones catalyzed by the Jacobsen catalyst occurs cleanly in the presence of hydrogen peroxide, sodium hypochlorite or iodosylbenzene as the stoichiometric oxidant. Meso 3,4-cis-isopropylidenedioxy-1-hydro

Synthesis of a new chiral pyrrolidine

The synthesis of a new chiral pyrrolidine has been performed using 2,3-O-isopropylidene-D-erythronolactol as a suitable starting material.

One-pot synthesis of cyclic nitrones and their conversion to pyrrolizidines: 7a-epi-crotanecine inhibits α-mannosidases

A new straightforward and inexpensive one-pot procedure is described for the preparation of enantiopure five-membered cyclic nitrones starting from the corresponding lactols. Its efficiency relies on the condensation of unprotected hydroxylamine with read

TBAT-mediated nitrone formation of ω-mesyloxy-O-tert-butyldiphenylsilyloximes: Facile synthesis of cyclic nitrones from hemiacetals

Chiral and cyclic nitrones were synthesized by TBAT-mediated desilylative cyclization of ω-mesyloxy-O-tert-butyl-diphenylsilyloximes, readily prepared from sugar derivatives by a consecutive treatment with O-tert-butyldiphenylsilylhydroxylamine and with m