223463-13-6Relevant articles and documents
Improved synthesis of 5,5"-dibromo-2,2′:6′,2"-terpyridine
Colasson, Beno?t X.,Dietrich-Buchecker, Christiane,Sauvage, Jean-Pierre
, p. 271 - 272 (2002)
5,5"-dibromo-2,2′:6′,2"-terpyridine has been synthesized in very good yield and on a multigram scale modifying the Stille cross-coupling strategy published by Schlüter and coworkers in a previous work.
Direct Transformation of Arylamines to Aryl Halides via Sodium Nitrite and N-Halosuccinimide
Mukhopadhyay, Sushobhan,Batra, Sanjay
supporting information, p. 14622 - 14626 (2018/09/21)
A one-pot universal approach for transforming arylamines to aryl halides via reaction with sodium nitrite (NaNO2) and N-halosuccinimide (NXS) in DMF at room temperature under metal- and acid-free condition is described. This new protocol that is complementary to the Sandmeyer reaction, is suggested to involve the in situ generation of nitryl halide induce nitrosylation of aryl amine to form the diazo intermediate which is halogenated to furnish the aryl halide.
Hybrid charged heterometallic Pt-Ir complexes: Tailoring excited states by taking the best of both worlds
Soliman, Ahmed M.,Fortin, Daniel,Harvey, Pierre D.,Zysman-Colman, Eli
supporting information; experimental part, p. 1120 - 1122 (2012/03/10)
The CC-linkage of Pt(PR3)2(CCAr)2 with (CN)2Ir(NN)+ (CN = 2-phenylpyridine; NN = bipyridyl) leads to hetero-bi- and trimetallic species exhibiting photophysical properties reminiscent of both [Pt]- and [Ir]-containing moieties through the generation of a [Pt] → [Ir] charge transfer excited state. The Royal Society of Chemistry 2012.