225656-35-9

Basic information

• Product Name: methyl (S)-2-methyl-2-(toluenesulfonylamino)-4-pentenoate
• Synonyms: methyl (S)-2-methyl-2-(toluenesulfonylamino)-4-pentenoate
• CAS NO: 225656-35-9
• Molecular Weight: 297.375
• Mol File: 225656-35-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: methyl (S)-2-methyl-2-(toluenesulfonylamino)-4-pentenoate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl (S)-2-methyl-2-(toluenesulfonylamino)-4-pentenoate(225656-35-9)
• EPA Substance Registry System: methyl (S)-2-methyl-2-(toluenesulfonylamino)-4-pentenoate(225656-35-9)

Safety Data

• Hazardous Substances Data: 225656-35-9(Hazardous Substances Data)

Upstream product

• 96886-55-4 (S)-α-allylalanine 
• 98-59-9 p-toluenesulfonyl chloride 
• 88820-87-5 (S)-2-Amino-2-(2-propenyl)propionsaeure-methylester 

Relevant articles and documents

Stereoselective lodocyclization of (S)-allylalanine derivatives: γ-lactone vs cyclic carbamate formation

An efficient procedure for highly chemo- and stereoselective cyclization of (S)-allylalanine derivatives is reported (diastereomeric ratios up to 96:4) where the reaction course can be completely controlled by switching from γ-lactones to cyclic carbamate