24182-84-1

Basic information

• Product Name: Benzene, 1-methyl-4-[(2-phenylethenyl)thio]-, (E)-
• CAS NO: 24182-84-1
• Molecular Formula: C15H14S
• Molecular Weight: 226.342
• Mol File: 24182-84-1.mol
• Article Data: 38

Chemical Properties

• CAS DataBase Reference: Benzene, 1-methyl-4-[(2-phenylethenyl)thio]-, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-methyl-4-[(2-phenylethenyl)thio]-, (E)-(24182-84-1)
• EPA Substance Registry System: Benzene, 1-methyl-4-[(2-phenylethenyl)thio]-, (E)-(24182-84-1)

Safety Data

• Hazardous Substances Data: 24182-84-1(Hazardous Substances Data)

Upstream product

• 103-19-5 di(p-tolyl) disulfide 
• 536-74-3 phenylacetylene 
• 106-45-6 para-thiocresol 
• 100-42-5 styrene 
• 934-72-5 Methyl p-tolyl sulfoxide 
• 63707-12-0 1-(4-methylphenylsulfanyl)-2-phenylethyne 
• 38986-89-9 trans-cinnamoyl fluoride 
• 6783-05-7 trans-2-phenylvinylboronic acid 
• 2757-04-2 phenyl cinnamate 
• 2943-42-2 di(4-methyl)phenylthiosulfonate 
• 83947-56-2 4,4,5,5-tetramethyl-2-((E)-styryl)-[1,3,2]dioxaborolane 
• 1576-35-8 toluene-4-sulfonic acid hydrazide 
• 588-72-7 [(E)-2-bromoethenyl]benzene 
• 1427290-14-9 1-(phenylseleno)-1,1-(S_S,S_S)-bis(p-tolylsulfinyl)methane 

Downstream Products

• 479623-83-1 (+/-)-(Z)-5-phenyl-4-(p-tolylsulfenyl)pent-4-en-3-ol 
• 1068599-48-3 CH₃C₆H₄SCHCH₂C₆H₅BO₂C₆H₄ 
• 156575-59-6 2-(2-phenylethyl)benzo-1,3,2-dioxaborole 
• 174090-36-9 4,4,5,5-tetramethyl-2-(1-phenyl-ethyl)-[1,3,2]dioxaborolane 
• 165904-22-3 4,4,5,5-tetramethyl-2-phenethyl-1,3,2-dioxaborolane 
• 1068599-50-7 CH₃C₆H₄SCH₂CHBO₂C₆H₄C₆H₅ 
• 156575-60-9 2-(1-phenyl-ethyl)-benzo[1,3,2]dioxaborole 
• 19062-76-1 (1-phenyl-2-tosylethyl)-(p-tolyl)sulfane 
• 211929-53-2 (2-tosylethane-1,1-diyl)dibenzene 
• 19719-87-0 1-methyl-4-(phenethylsulfonyl)benzene 
• 2779-69-3 1,1-dichloro-2,2-diphenylethene 

Relevant articles and documents

Transition Metal-Free C-H Thiolation via Sulfonium Salts Using β-Sulfinylesters as the Sulfur Source

We disclose a direct C(sp)-, C(sp2)-, and C(sp3)-H thiolation reaction using β-sulfinylesters as the versatile sulfur source. The key step of this protocol is chemoselective C-S bond cleavage of the sulfonium salts that are formed in situ from the corresponding alkenes, alkynes, and 1,3-dicarboxyl compounds with β-sulfinylesters. The successful capture of the acrylate byproduct supports a retro-Michael reaction mechanism.

Nickel-Catalyzed Decarbonylative Thioetherification of Acyl Fluorides via C-F Bond Activation

Nickel-catalyzed decarbonylative thioetherification of acyl fluorides has been developed. This transformation allows an array of acyl fluorides to react with thiophenols. A wide range of functional groups are well tolerated and the corresponding sulfides can be obtained in good to excellent yields. This protocol provides the formation of diverse carbon-sulfur bonds via a highly efficient decarbonylative process.

Anti-Markovnikov stereoselective hydroamination and hydrothiolation of (hetero)aromatic alkynes using a metal-free cyclic trimeric phosphazene base

Hydroamination and hydrothiolation are the most efficient and completely atom-economical process to construct important enamine and vinyl sulfide intermediates in pharmaceutical and organic chemistry. The cyclic trimeric phosphazene base (CTPB) showed gre