2513-64-6Relevant articles and documents
Heterocyclic spirocyclohexadienones, I
Mohrle,Schake,Bluhme-Hensen
, p. 665 - 670 (1992)
The compound formerly described as methylene amine 3 is in fact the heterocyclic spirocyclohexadienone 9. Contrary to literature, catalytic hydrogenation does not lead to methylamine 4 but to spiroketone 10 and a mixture of diastereomeric spirocyclic alco
A general catalytic methylation of amines using carbon dioxide
Li, Yuehui,Fang, Xianjie,Junge, Kathrin,Beller, Matthias
supporting information, p. 9568 - 9571 (2013/09/23)
Putting CO2 to work: Carbon dioxide is shown to be a general and selective methylating reagent for secondary and primary, aromatic and aliphatic amines under reductive conditions. A variety of tertiary amines are obtained from CO2 and commercially available silanes in high yields with good tolerance to nitrile, olefin, ether, ester, and hydroxy groups. Copyright
Generation and Reactions of Nonstabilized Bis(α-amino carbanions)
Katrjtzky, Alan R.,Qi, Ming,Feng, Darning
, p. 6712 - 6714 (2007/10/03)
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