253662-87-2Relevant articles and documents
An effective method for the preparation of optically active polyoxy 8-membered ring enone corresponding to the B ring of taxol
Shiina, Isamu,Shibata, Jun,Imai, Yumiko,Ibuka, Ryoutarou,Fujisawa, Hidehiko,Hachiya, Iwao,Mukaiyama, Teruaki
, p. 1145 - 1146 (1999)
An effective method for the preparation of 8-membered ring enone 1 in sufficient quantities was developed. First, optically active trialkoxyaldehyde 3 was prepared by diastereoselective dihydroxylation of olefin 7 derived from D-pantolactone. Secondly, 8-