26227-54-3Relevant articles and documents
Control of the white-light emission in the mixed two-dimensional hybrid perovskites (C6H11NH3)2[PbBr4?xIx]
Yangui, Aymen,Pillet, Sebastien,Lusson, Alain,Bendeif, El-Eulmi,Triki, Smail,Abid, Younes,Boukheddaden, Kamel
, p. 1122 - 1133 (2017)
The control of the composition of mixed organic-inorganic hybrid perovskites by solid-state alloying is a very efficient tool to tune the band gap of the material, leading to enhanced optical performances. At this end, we have elaborated a series of mixed-halide two-dimensional hybrid perovskites (C6H11NH3)2[PbBr4?xIx], with 0 ≤ x ≤ 4, for which we studied the composition-dependence of the structural parameters and their effect on the white-light luminescence properties at room temperature. The structural analysis revealed the existence of a composition-induced structural phase transition occurring in the range 2 a change between Cmc21and Pbca space groups. The optical properties, investigated using optical absorption and photoluminescence measurements, have shown that bromine (Br) to iodine (I) halogen ion substitution redshifts the excitonic optical absorption band, as a result of the hybridization of the valence band structure, built from np orbitals of Br and/or I halogens and 6s orbitals of lead. When iodine was predominant (x > 2), the photoluminescence spectra showed a sharp peak with a relatively small Stokes shift (less than 0.2 eV) attributed to free or bound excitons emissions. In contrast, when the bromide is majority (x a broadband white-light emission with a very large Stokes shift (between 1.2 eV and 0.3 eV), attributed to self-trapped excitons activated by a strong structural distortion of the inorganic sheets. Confronting optical and structural data highlighted the effect of the structure in monitoring the optical properties, since the intensity of the white-light emission increases with the bromine content and was found to excellently correlate with the change of the angular distortion of inorganic octahedra PbX6(X = I/Br).
OPTICALLY ACTIVE TRIORGANOSILYL ESTERS OF PHOSPHORUS. SYNTHESIS AND STRUCTURE
Chojnowski, J.,Cypryk, M.,Michalski, J.,Wozniak, L.,Corriu, R.,Lanneau, G.
, p. 385 - 398 (2007/10/02)
We report this synthesis of the first optically active silyl esters of phosphorus having two centres of chirality : one on silicon and the other on phosphorus.Compounds are obtained of general formula : t-BuPhP(X)YSiαNpPhMe X,Y=O, O(1); S, O(2); Se, O(3); S, S(4); doublet, O(5) including 1 and 3 with optical activity located on Si, 2 and 5 with the activity on Si or P and on both these centres, 4 only racemic.Absolute configurations are determined. 31P and 29Si NMR spectra of these models and their trimethylsilyl analogues are reported.The triorganosilyl group is always preferentially bound to phosphorus through oxygen atom.Surprisingly, diastereotopic NMR chemical shifts exclude the fast 1,3 migration in esters 1 and 4. 29Si NMR spectra correspond to a tetracoordinate silicon atom.
OXALSAEUREDERIVATE DURCH OXIDATIVE KUPPLUNG VON KOHLENMONOXID AN NICKEL
Hoberg, Heinz,Fananas, F. Javier,Riegel, Hans Josef
, p. 267 - 272 (2007/10/02)
Carbon monoxide is oxidatively coupled by ligand nickel(II) compounds with secondary, primary amines and with alkali alkoxides to give oxalic acid derivatives.In the case of secondary amines the CO coupling can be run catalytically by adding oxidants like copper(II) salts.The yield of oxalic esters depends on the types of ligands and anions.