27962-41-0

Basic information

• Product Name: α-butylbenzoin
• Synonyms: α-butylbenzoin
• CAS NO: 27962-41-0
• Molecular Weight: 268.356
• Mol File: 27962-41-0.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: α-butylbenzoin(CAS DataBase Reference)
• NIST Chemistry Reference: α-butylbenzoin(27962-41-0)
• EPA Substance Registry System: α-butylbenzoin(27962-41-0)

Safety Data

• Hazardous Substances Data: 27962-41-0(Hazardous Substances Data)

Upstream product

• 693-03-8 n-butyl magnesium bromide 
• 134-81-6 benzil 
• 1191-47-5 dibutylmagnesium 
• 1461-25-2 tetra-n-butyltin(IV) 
• 1528-00-3 di-n-butyldimethylstannane 
• 101098-28-6 di-n-butyl(diisopropyl)tin 
• 30191-50-5 (C₄H₉)2Sn(tert-C₄H₉)2 
• 542-69-8 1-iodo-butane 
• 119-53-9 2-hydroxy-2-phenylacetophenone 
• 164662-96-8 1-trimethylsilyl-2-(tributylstannyl)methyl-2-propene 

Relevant articles and documents

Cleavage of Tin-Carbon Bonds of Organosilylstannane and Organodistannane in Photo-Induced Electron Transfer Reaction and Mass Spectrometry

Photoalkylation of tetracyanobenzene and benzil with (n-Bu)3SnSiMe3 or (n-Bu)3SnSn(n-Bu)3 proceeds via electron transfer.In these reactions, the Sn-C bond of (n-Bu)3SnSiMe3 and (n-Bu)3SnSn(n-Bu)3 is cleaved in preference to the Sn-Si and Sn-Sn bonds.Similar cleavage of the Sn-C bond is also observed in mass spectra of these group 14 organometallic compounds.

Photoalkylation of α-Diketones with Tetraalkylstannanes via Electron Transfer

Irradiation of α-diketones in the presence of tetraalkylstannanes gave α-ketols via electron transfer.The analogy between the photo-induced electron transfer reactions and mass spectrometry exists in the fragmentation of the radical cation of the stannanes.