29000-10-0

Basic information

• Product Name: Stannane, triphenyl(3-phenyl-2-propenyl)-, (E)-
• CAS NO: 29000-10-0
• Molecular Formula: C27H24Sn
• Molecular Weight: 467.198
• Mol File: 29000-10-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Stannane, triphenyl(3-phenyl-2-propenyl)-, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: Stannane, triphenyl(3-phenyl-2-propenyl)-, (E)-(29000-10-0)
• EPA Substance Registry System: Stannane, triphenyl(3-phenyl-2-propenyl)-, (E)-(29000-10-0)

Safety Data

• Hazardous Substances Data: 29000-10-0(Hazardous Substances Data)

Upstream product

• 962-89-0 triphenyltin bromide 
• 131131-39-0 3-phenylpropen-1-yl magnesium chloride 
• 19752-28-4 1-phenylprop-2-enyl(triphenyl)stannane 
• 161838-12-6 (C₆H₅)3SnCH₂CHCHC₆H₅ 

Downstream Products

• 31262-09-6 trans-Cinnamyl-diphenylboran 
• 84363-86-0 (±)-anti-1,4-diphenylhex-5-en-3-ol 
• 84363-90-6 (1RS,2SR)-1,2-diphenyl-3-buten-1-ol 
• 40596-14-3 anti-3-phenyl-4-hydroxy-1-pentene 
• 84363-88-2 (1RS,2RS)-1-cyclohexyl-2-phenylbut-3-en-1-ol 
• 133039-10-8 1-cinnamyl-2,4,6-trimethylbenzene 
• 40596-14-3 (±)-(2R,3S)-3-phenylpent-4-en-2-ol 
• 54848-80-5 1-Nitro-2-(1-phenyl-allylsulfanyl)-benzene 
• 205485-72-9 (Z)-cinnamyl(triphenyl)stannane 
• 1064-10-4 hexaphenylditin 
• 19752-28-4 1-phenylprop-2-enyl(triphenyl)stannane 
• 639-58-7 triphenyltin chloride 

Relevant articles and documents

Photochemical 1,3-stannyl rearrangement of allylic stannanes

The photochemical 1,3-stannyl rearrangement of allylic stannanes has been investigated. The photorearrangement of (E)-cinnamyl(triphenyl)stannane is not observed in benzene under anaerobic conditions, while the photoinduced 1,3-stannyl migration takes place in the same solvent under aerobic conditions, or in the presence of organic halides or a radical-trapping agent to give a photoequllibrium mixture of the cinnamylstannane and its branched regioisomer, 1-phenylprop-2-enyl(triphenyl)stannane, with the latter predominating. Cinnamyl(trialkyl)stannanes and their homologues also afford the corresponding branched allylstannanes under similar photochemical conditions. These 1,3-stannyl migrations proceed intramolecularly via cinnamyl π-π* excitation in competition with homolytic (cinnamyl)C-Sn bond fission. In contrast, the 1,3-stannyl migration of crotyl- and prenyl-(tributyl)-stannanes is not efficient, but their triphenyl or dibutylphenyl derivatives undergo the 1,3-rearrangement via excitation of the phenyl group(s) on the tin atom to give a regioisomeric mixture of the starting linear tin compounds and the branched ones with the former predominating.