301164-69-2Relevant articles and documents
Synthesis and electrochemical polymerization of a novel 2-(thiophen-2-yl)-4-(thiophen-2-ylmethylene)oxazol-5(4H)-one monomer for supercapacitor applications
Hür, Evrim,Arslan, Anda?,Hür, Deniz
, p. 35 - 41 (2016)
In this study, the organic synthesis, electrochemical polymerization and electrochemical characterization of a novel 2-(thiophen-2-yl)-4-(thiophen-2-ylmethylene)oxazol-5(4H)-one, 3, monomer have been reported for supercapacitor applications. Electrode active material was formed electrochemically coating of poly(2-(thiophen-2-yl)-4-(thiophen-2-ylmethylene)oxazol-5(4H)-one) (PTTMO) on pencil graphite electrode (PGE). Electrochemical polymerization was carried out by chronoamperometric (CA) technique in an acetonitrile (ACN) solution containing 0.01 M monomer and 0.10 M tetrabuthylammonium perchlorate (TBAP). The prepared PGE/PTTMO electrode has been monitored by scanning electron microscopy (SEM). Electrochemical properties of the electrode have been investigated by CV, electrochemical impedance spectroscopy (EIS), galvanostatic charge-discharge and repeating chronopotentiometry (RCP) techniques with two or three electrode systems. PGE/PTTMO has exhibited a capacitive performance with highest specific capacitances of 193.00 F g- 1 at a scan rate of 10 mV s- 1. On the other hand, the electrode has shown good charge-discharge cycling stability with the retained ratio about 90.83%.
Visible-Light-Induced C(sp2)-P Bond Formation by Denitrogenative Coupling of Benzotriazoles with Phosphites
Jian, Yong,Chen, Ming,Huang, Binbin,Jia, Wei,Yang, Chao,Xia, Wujiong
supporting information, p. 5370 - 5374 (2018/09/13)
A visible-light-induced denitrogenative phosphorylation of benzotriazoles is presented, in which diverse substituted aryl phosphonates could be obtained in good to excellent yields. This efficient protocol exhibits good tolerance with various functional g
Preparation of polyfunctional acyl azides
Katritzky, Alan R.,Widyan, Khalid,Kirichenko, Kostyantyn
, p. 5802 - 5804 (2008/02/09)
(Chemical Equation Presented) A general synthesis of acyl azides from the corresponding N-acyl benzotriazoles is described. The procedure affords acyl azides in good yields and avoids the use of acid activators and NO+ equivalents typically emp