31675-43-1

Basic information

• Product Name: Phosphonic acid, [phenyl[(trimethylsilyl)oxy]methyl]-, diethyl ester
• CAS NO: 31675-43-1
• Molecular Formula: C14H25O4PSi
• Molecular Weight: 316.409
• Mol File: 31675-43-1.mol
• Article Data: 15

Chemical Properties

• CAS DataBase Reference: Phosphonic acid, [phenyl[(trimethylsilyl)oxy]methyl]-, diethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Phosphonic acid, [phenyl[(trimethylsilyl)oxy]methyl]-, diethyl ester(31675-43-1)
• EPA Substance Registry System: Phosphonic acid, [phenyl[(trimethylsilyl)oxy]methyl]-, diethyl ester(31675-43-1)

Safety Data

• Hazardous Substances Data: 31675-43-1(Hazardous Substances Data)

Upstream product

• 100-52-7 benzaldehyde 
• 13716-45-5 diethyl trimethylsilyl phosphite 
• 75-77-4 chloro-trimethyl-silane 
• 762-04-9 phosphonic acid diethyl ester 
• 122-52-1 triethyl phosphite 
• 1663-55-4 diethyl [hydroxy(phenyl)methyl]phosphonate 
• 999-97-3 1,1,1,3,3,3-hexamethyl-disilazane 
• 5908-41-8 benzoyltrimethylsilane 
• 51523-27-4 (diethoxy)phosphine 
• 51523-25-2 Diethyl-(trimethylsilylamido)-phosphit 
• 3385-94-2 hexamethyldisilathiane 

Downstream Products

• 4521-08-8 3-methyl-2-phenylbenzofuran 
• 74552-58-2 2-Hydroxy-2-(2-methoxyphenyl)-2-methyl-1-phenylethanone 
• 28698-05-7 α-(trimethylsiloxy)-1,1-diphenylmethyl phenyl ketone 
• 66731-85-9 (1-Phenyl-1-trimethylsilanyloxy-pentyl)-phosphonic acid diethyl ester 
• 344572-61-8 ((E)-4,8-Dimethyl-1-phenyl-1-trimethylsilanyloxy-nona-3,7-dienyl)-phosphonic acid diethyl ester 
• 95800-09-2 1-benzoyl-1-(trimethylsiloxy)cyclobutane 
• 24534-44-9 2,6-Diphenylbenzo<1,2-b:5,4-b'>difuran 
• 74888-52-1 2-Hydroxy-1-phenyl-nonan-1-one 
• 56345-98-3 α-(trimethylsiloxy)-1-cyclohexyl phenyl ketone 
• 947-19-3 1-hydroxycyclohexyl phenyl ketone 
• 26205-39-0 1,2-diphenyl-2-(trimethylsilyloxy)ethanone 
• 119-53-9 2-hydroxy-2-phenylacetophenone 
• 74552-49-1 Diethyl 2-hydroxy-1-(trimethylsiloxy)-1,2-diphenylethanephosphonate 
• 66731-83-7 (1-Phenyl-1-trimethylsilanyloxy-propyl)-phosphonic acid diethyl ester 

Relevant articles and documents

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One-pot synthesis of primary 1-aminophosphonates: Coupling reaction of carbonyl compounds, hexamethyldisilazane, and diethyl phosphite catalyzed by al(otf)3

Al(OTf)3 has been utilized as a new and efficient catalyst for the selective synthesis of primary 1-aminophosphonates by a one-pot coupling reaction of various types of aldehydes/ketones, hexamethyldisilazane, and diethyl phosphite under solvent-free cond

Synthesis of functionalized 1-trimethylsiloxy-substituted O-trimethylsilyl alkylphosphonites and their derivatives

Nucleophilic addition of trimethylsilyl esters of tricoordinate organophosphorus acids to various functionalized aldehydes with vinyl, aryl, and heterocyclic fragments is proposed as a convenient method for the synthesis of new 1-trimethylsiloxysubstituted alkylphosphonites and their derivatives at mild conditions. Also the new functionalized derivatives of these phosphonites, including amino groups as well as certain properties of these compounds as important precursors of new functionalized 1-hydroxyalkylorganophosphorus acids, are presented.