31900-57-9Relevant articles and documents
METHOD FOR PRODUCING SILANOLS AND NOVEL SILANOLS
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Paragraph 0053-0054; 0057-0058, (2021/08/13)
PROBLEM TO BE SOLVED: To provide a method for efficiently producing silanols useful as functional chemicals, and to provide novel silanols. SOLUTION: There is provided a method for producing silanols including a reaction step of reacting alkoxysilanes having Si-OR bonds (R represents a hydrocarbon group having 1 to 6 carbon atoms) with water or heavy water in the presence of a catalyst, wherein a method for producing silanols having an Si-OR' bond (R' represents a hydrogen atom or a deuterium atom) is characterized in that the catalyst is an inorganic solid acid catalyst having a regular pore structure. There is also provided novel silanols obtained thereby. SELECTED DRAWING: None COPYRIGHT: (C)2021,JPOandINPIT
Effect of Silyl Ether-functinoalized Dimethoxydimethylsilane on Electrochemical Performance of a Ni-rich NCM Cathode
Jang, Seol Heui,Yim, Taeeun
, p. 3402 - 3406 (2017/12/15)
Dimethoxydimethylsilane (DODSi) is used as an interface stabilizing additive through a selective HF scavenging reaction for layered Ni-rich oxide cathodes. Ex situ NMR analyses demonstrated that DODSi effectively removes HF from the electrolyte based on the matched chemical reactivity of Si with F? and O with H+. The cells employing DODSi exhibit higher specific capacity with retention than those cycled with a DODSi-free electrolyte even under in situ HF generating conditions. Scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), and inductively coupled plasma-mass spectroscopy (ICP-MS) analyses indicate that DODSi effectively protects the Ni-rich oxide cathodes against HF corrosion, resulting in improved surface stability of Ni-rich cathodes.
Formation of silicones mediated by the sponge enzyme silicatein-α
Wolf, Stephan E.,Schlossmacher, Ute,Pietuch, Anna,Mathiasch, Bernd,Schroeder, Heinz-C.,Mueller, Werner E. G.,Tremel, Wolfgang
experimental part, p. 9245 - 9249 (2011/01/11)
The sponge-restricted enzyme silicatein-α catalyzes in vivo silica formation from monomeric silicon compounds from sea water (i.e. silicic acid) and plays the pivotal role during synthesis of the siliceous sponge spicules. Recombinant silicatein-α, which was cloned from the demosponge Suberites domuncula (phylum Porifera), is shown to catalyze in vitro condensation of alkoxy silanes during a phase transfer reaction at neutral pH and ambient temperature to yield silicones like the straight-chained polydimethylsiloxane (PDMS). The reported condensation reaction is considered to be the first description of an enzymatically enhanced organometallic condensation reaction. The Royal Society of Chemistry.