322474-86-2Relevant articles and documents
Stereocontrolled synthesis and configurational assignment of (R)-all-trans-11,12-dihydro-3-hydroxyretinol
Rivas,Alvarez, Rosana,de Lera, Angel R.
, (2019/08/07)
The synthesis of (R)-all-trans-11,12-dihydro-3-hydroxyretinol and putative metabolites of the side-chain functional group has been achieved in a stereocontrolled manner via the Suzuki-Hiyama cross-coupling reaction of an enantiopure (hydroxycyclohexenyl)alkenyliodide and non-conjugated pinacolboranedienoate, which allowed the absolute configuration of this natural product to be confirmed.
The Stille reaction in the synthesis of the C37-norcarotenoid butenolide pyrrhoxanthin. Scope and limitations
Vaz, Belen,Dominguez, Marta,Alvarez, Rosana,De Lera, Angel R.
, p. 5914 - 5920 (2007/10/03)
The sequential Stille cross-coupling reactions of the dihalogenated γ-alkylidenebutenolide 7 with stannanes 9 and 6 afforded the carbon skeleton of pyrrhoxanthin, a highly functionalized C7′-C8′ acetylenic C37-norcarotenoid butenolide. Although
First total synthesis of crassostreaxanthin B
Tode, Chisato,Yamano, Yumiko,Ito, Masayoshi
, p. 1625 - 1626 (2007/10/03)
The first total synthesis of crassostreaxanthin B 1 was accomplished via the tetrasubstituted olefinic compound 5, prepared by stereoselective rearrangement of epoxides 3a,b using a Lewis acid.