32507-45-2Relevant articles and documents
Iron(III)/O2-Mediated Regioselective Oxidative Cleavage of 1-Arylbutadienes to Cinnamaldehydes
Bhowmik, Amit,Fernandes, Rodney A.
supporting information, p. 9203 - 9207 (2019/11/14)
A simple, efficient, and environmentally benevolent regioselective oxidative cleavage of 1-arylbutadienes to cinnamaldehydes mediated by iron(III) sulfate/O2 has been developed. The reaction offered good yields and excellent regioselectivity and showed good functional group tolerance (31 examples). The method is important, as few reports with limited substrate scope are available for such excellent oxidative cleavage of conjugated dienes.
Titanium-catalyzed intermolecular hydroaminoalkylation of conjugated dienes
Preuss, Till,Saak, Wolfgang,Doye, Sven
, p. 3833 - 3837 (2013/04/24)
Ti me kangaroo down: Conjugated dienes undergo intermolecular hydroaminoalkylation in the presence of Ti catalyst [Ind2TiMe 2] (Ind=η5-indenyl). This new reaction offers a highly atom-efficient approach to homoallylic amines from 1,3-butadienes. Copyright
Boron trihalide mediated haloallylation of aryl aldehydes and its application to the preparation of (E)-1,3-dienes
Quinn, Michael P.,Yao, Min-Liang,Yong, Li,Kabalka, George W.
, p. 3815 - 3820 (2012/01/05)
In the presence of boron trihalides, aryl aldehydes couple readily with allylmetals to afford haloallylated products. The reactions tolerate a variety of functional groups. Simple aqueous workup of haloallylation reactions, followed by treatment with 1,8-
