32785-99-2

Basic information

• Product Name: 6-Deoxy-1-O,2-O:3-O,5-O-bis(isopropylidene)-α-D-glucofuranose
• Synonyms: 6-Deoxy-1-O,2-O:3-O,5-O-bis(isopropylidene)-α-D-glucofuranose
• CAS NO: 32785-99-2
• Molecular Formula: C12H20O5
• Molecular Weight: 244.2842
• Mol File: 32785-99-2.mol
• Article Data: 4

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 6-Deoxy-1-O,2-O:3-O,5-O-bis(isopropylidene)-α-D-glucofuranose(CAS DataBase Reference)
• NIST Chemistry Reference: 6-Deoxy-1-O,2-O:3-O,5-O-bis(isopropylidene)-α-D-glucofuranose(32785-99-2)
• EPA Substance Registry System: 6-Deoxy-1-O,2-O:3-O,5-O-bis(isopropylidene)-α-D-glucofuranose(32785-99-2)

Safety Data

• Hazardous Substances Data: 32785-99-2(Hazardous Substances Data)

Upstream product

• 16749-46-5 6-deoxy-1,2-O-isopropylidene-β-L-idofuranose 
• 17668-66-5 6-deoxy-1,2-O-isopropylidene-α-D-glucofuranose 
• 34322-91-3 1,2:3,5-bis-O-(1-methylethylidene)-6-(p-tolylsulfonyl)-α-D-glucofuranose 
• 38838-11-8 6-bromo-6-deoxy-1,2:3,5-di-O-isopropylidene-α-D-glucofuranose 
• 24877-08-5 1,2:3,5-di-O-isopropylidene-6-deoxy-6-iodo-α-D-glucofuranose 
• 26275-20-7 6-deoxy-1,2-O-isopropylidene-6-(4'-methylbenzene)sulfonyloxy-D-glucofuranose 
• 582-52-5 1,2:5,6-di-O-isopropylidene-α-D-glucofuranose 
• 18549-40-1 1,2-O-isopropylidene-α-D-glucofuranose 
• 7595-86-0 O³,O⁵-((Ξ)-benzylidene)-O¹,O²-isopropylidene-O⁶-(toluene-4-sulfonyl)-α-D-glucofuranose 
• 194875-04-2 O³,O⁵-((Ξ)-benzylidene)-O¹,O²-isopropylidene-6-iodo-6-deoxy-α-D-glucofuranose 
• 19189-71-0 O³,O⁵-((Ξ)-benzylidene)-O¹,O²-isopropylidene-α-D-xylo-6-deoxy-hex-5-enofuranose 
• 81562-09-6 6-hydroxy-1,2:3,5-di-O-isopropylidene-α-D-glucofuranoside 
• 258521-65-2 6-tosyl-1,2:3,5-di-O-isopropylidene-β-L-idofuranoside 
• 87357-54-8 6-deoxy-1,2:3,5-di-O-isopropylidene-α-D-xylo-hex-5-enofuranose 

Downstream Products

• 16749-46-5 6-deoxy-1,2-O-isopropylidene-β-L-idofuranose 
• 17668-66-5 6-deoxy-1,2-O-isopropylidene-α-D-glucofuranose 

Relevant articles and documents

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Biologically potent L-hexoses and 6-deoxy-L-hexoses: Their syntheses and applications

This account describes our recent work in the development of new methodologies to prepare rare and biologically potent L-hexoses and 6-deoxy-L-hexoses, from cheapest D-glucose, via L-hexofuranoses and 1,6-anhydro-β-L-hexopyranoses as key building blocks. Their applications in the syntheses of heparin oligosaccharides, the carbohydrate moiety of bleomycin A2, and L-acovenose are also summarized here.

Novel synthesis of 1,2:3,5-di-O-isopropylidene-β-L-idofuranoside and its derivatives at C6

An efficient synthesis of 1,2:3,5-di-O-isopropylidene-β-L-idofuranoside and its derivatives at C6 from diacetone α-D-glucose employing the stereoselective hydroboration and hydrogenation as key steps is described here.