33152-09-9

Basic information

• Product Name: (CH₂CH₂)2NiP(C₆H₁₁-cyclo)3
• CAS NO: 33152-09-9
• Molecular Weight: 395.231
• Mol File: 33152-09-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (CH₂CH₂)2NiP(C₆H₁₁-cyclo)3(CAS DataBase Reference)
• NIST Chemistry Reference: (CH₂CH₂)2NiP(C₆H₁₁-cyclo)3(33152-09-9)
• EPA Substance Registry System: (CH₂CH₂)2NiP(C₆H₁₁-cyclo)3(33152-09-9)

Safety Data

• Hazardous Substances Data: 33152-09-9(Hazardous Substances Data)

Upstream product

• 50696-82-7 tris(ethene)nickel⁽⁰⁾ 
• 2622-14-2 tricyclohexylphosphine 
• 74-85-1 ethene 
• 37249-40-4 π(-trans-trans-trans-cyclododeca-1,5,9-triene)NiP(C6H11-cyclo)3 
• 29046-78-4 (1,2-dimethoxyethane)dichloronickel(II) 

Downstream Products

• 121191-92-2 tricyclohexylphosphane(ethene)(ethyne)nickel⁽⁰⁾ 
• 18475-08-6 (tricyclohexylphosphane)Ni⁽⁰⁾(CO)3 
• 41685-59-0 ethene-bis(tricyclohexylphosphane)-nickel(0) 
• 32104-66-8 bis(1,2-bis(dimethylphosphino)ethane)nickel(II) 

Relevant articles and documents

Simplified and versatile access to low valent Ni complexes by metal-free reduction of NiII precursors

The reduction of [Ni(DME)Cl2] with 2 equiv. of bis(trimethylsilyl)-1,4-tetramethyldihydropyrazine in the presence of a ligand L and an excess of olefin cleanly leads to [Ni(L)(alkene)2] complexes. When reduction is performed in the presence of 1,5-cyclooctadiene (COD), [Ni(COD)2] is obtained. Such an approach also allows access to the NiI dimer [Ni(bis(dicyclohexylphosphino)propane)Cl]2.