41685-59-0

Basic information

• Product Name: ethene-bis(tricyclohexylphosphane)-nickel(0)
• Synonyms: ethene-bis(tricyclohexylphosphane)-nickel(0)
• CAS NO: 41685-59-0
• Molecular Weight: 647.611
• Mol File: 41685-59-0.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: ethene-bis(tricyclohexylphosphane)-nickel(0)(CAS DataBase Reference)
• NIST Chemistry Reference: ethene-bis(tricyclohexylphosphane)-nickel(0)(41685-59-0)
• EPA Substance Registry System: ethene-bis(tricyclohexylphosphane)-nickel(0)(41685-59-0)

Safety Data

• Hazardous Substances Data: 41685-59-0(Hazardous Substances Data)

Upstream product

• 74-85-1 ethene 
• 501-65-5 diphenyl acetylene 
• 2622-14-2 tricyclohexylphosphine 
• 92998-03-3 ((CH₃)2PCH₂CH₂P(CH₃)2)(P(C₆H₁₁)3)Ni(C₂H₄) 
• 557-18-6 diethylmagnesium dioxane complex 
• 3264-82-2 nickel(II) acetylacetonate 
• 33152-09-9 (CH₂CH₂)2NiP(C₆H₁₁-cyclo)3 
• 23936-60-9 1,2-bis(dimethylphosphanyl)ethane 

Downstream Products

• 97959-89-2 {(tricyclohexylphosphine)(2,6-dimethyl-γ-pyrone)nickel} 
• 84651-73-0 NiC₆O₂(CH₃)4P(C₆H₁₁)3 
• 74910-03-5 [Ni(η2-benzaldehyde)(PCy3)2] 
• 74910-04-6 ((C₆H₁₁)3P)2NiOCHC₆H₃(OCH₃)2 
• 28796-12-5 (CO)2Ni(P(C₆H₁₁-cyclo)3)2 
• 71375-85-4 P(C₆H₁₁)3*Ni*CS₂ = (C₆H₁₁)3PNi(CS₂) 
• 172294-44-9 (η(2)-C6H8)Ni(P(C6H11)3)2 
• 79895-18-4 (PCy₃)Ni(COD) 
• 113095-51-5 {(cyclohexyl)3P}2Ni(HCCC₆H₅) 
• 84651-74-1 NiC₆O₂(C₄H₄)2(P(C₆H₁₁)3)2*(C₂H₅)2O 

Relevant articles and documents

Nickel-Catalyzed Formation of 1,3-Dienes via a Highly Selective Cross-Tetramerization of Tetrafluoroethylene, Styrenes, Alkynes, and Ethylene

In the presence of a catalytic amount of Ni(cod)2 (cod = 1,5-cyclooctadiene) and PCy3 (Cy = cyclohexyl), the cross-tetramerization of tetrafluoroethylene (TFE), alkynes, and ethylene occurred in a highly selective manner to afford a variety of 1,3-dienes with a 3,3,4,4-tetrafluorobutyl chain. In addition, a Ni(0)-catalyzed cross-tetramerization of TFE, alkynes, ethylene, and styrenes was developed. These catalytic reactions might proceed via partially fluorinated five- and seven-membered nickelacycle key intermediates.

Tris(phosphane)-nickel(0)-ethene Complexes (dmpe)(PR3)Ni(C2H4). Molecular Structure of (dmpe)(PPh3)Ni(C2H4)

Synthesis and properties of tris(phosphane)(ethene)nickel(0) complexes (dmpe)(PR3)Ni(C2H4) (R = CH3 (4), c-C6H11 (5), and C6H5 (6)) are reported.In solution, 4-6 are thermolabile and undergo ligand exchange reactions affording tetrakis(phosphane)nickel(0)