33558-55-3Relevant articles and documents
Me3Si?SiMe2[oCON(iPr)2?C6H4]: An Unsymmetrical Disilane Reagent for Regio- and Stereoselective Bis-Silylation of Alkynes
Xiao, Peihong,Cao, Yanjun,Gui, Yingying,Gao, Lu,Song, Zhenlei
supporting information, p. 4769 - 4773 (2018/03/21)
The air-stable unsymmetrical disilane Me3Si?SiMe2[oCON(iPr)2C6H4] has been developed for bis-silylation of alkynes. This reagent tolerates a range of functional groups, providing Z-vinyl disilanes in
Peculiarities in the cleavage by methyllithium of unsymmetrical disilanes
Hevesi,Dehon
, p. 8031 - 8032 (2007/10/02)
The title reactions did not produce the more stable silyl anions from the disilanes studied, they either occurred by attack at the more electrophilic silicon atom, or led to unexpected products.