3427-20-1

Basic information

• Product Name: methyl 4,6-di-O-acetyl-2,3-dideoxy-D-erythro-hex-2-enopyranoside
• Synonyms: methyl 4,6-di-O-acetyl-2,3-dideoxy-D-erythro-hex-2-enopyranoside
• CAS NO: 3427-20-1
• Molecular Weight: 244.244
• Mol File: 3427-20-1.mol
• Article Data: 44

Chemical Properties

• Boiling Point: 319.7±42.0 °C(Predicted)
• Density: 1.18±0.1 g/cm3(Predicted)
• CAS DataBase Reference: methyl 4,6-di-O-acetyl-2,3-dideoxy-D-erythro-hex-2-enopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 4,6-di-O-acetyl-2,3-dideoxy-D-erythro-hex-2-enopyranoside(3427-20-1)
• EPA Substance Registry System: methyl 4,6-di-O-acetyl-2,3-dideoxy-D-erythro-hex-2-enopyranoside(3427-20-1)

Safety Data

• Hazardous Substances Data: 3427-20-1(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 2873-29-2 D-glucal triacetate 
• 149-73-5 trimethyl orthoformate 
• 2873-29-2 Acetic acid (2S,3S,4S)-4-acetoxy-2-acetoxymethyl-3,4-dihydro-2H-pyran-3-yl ester 
• 2873-29-2 Acetic acid (2R,3S,4R)-4-acetoxy-2-acetoxymethyl-3,4-dihydro-2H-pyran-3-yl ester 
• 286410-13-7 phenyl 4,6-di-O-acetyl-2,3-dideoxy-D-erythro-1-thio-hex-2-enopyranoside 
• 572-09-8 2,3,4,6-tetra-O-acetyl-D-glucopyranosyl bromide 
• 2280-44-6 D-Glucose 
• 52485-06-0 3,4,6-tri-O-acetyl-D-glucal 
• 13322-91-3 4,6-Di-O-acetyl-2,3-didehydro-2,3-dideoxy-D-erythrohexosyl-fluorid 

Downstream Products

• 64551-84-4 methyl 4,6-di-O-acetyl-2,3-dideoxy-α-D-erythro-hexopyranoside 
• 143087-26-7 (4aR,8aS)-2,2-Dimethyl-6-phenylsulfanyl-hexahydro-pyrano[3,2-d][1,3]dioxine 
• 143087-25-6 Acetic acid (2R,3S)-2-acetoxymethyl-6-phenylsulfanyl-tetrahydro-pyran-3-yl ester 
• 143087-27-8 (4aR,8aS)-6-Benzenesulfonyl-2,2-dimethyl-hexahydro-pyrano[3,2-d][1,3]dioxine 
• 1310543-00-0 C₂₀H₂₃NO₆ 
• 93220-64-5 Methyl-4,6-di-O-acetyl-2,3-dideoxy-β-D-erythro-hex-2-enopyranosid 
• 861928-56-5 2-isopropyl-5-methylcyclohexyl-4,6-di-O-acetyl-2,3-dideoxy-α-D-erythrohex-2-enopyranoside 
• 93105-91-0 methyl-4-O-benzyl-6-O-(t-butyldiphenylsilyl)-2,3-dideoxy-α,β-D-erythro-hexopyranoside 
• 87316-21-0 methyl-6-O-(t-butyldiphenylsilyl)-2,3-dideoxy-α,β-D-erythro-hexopyranoside 
• 142573-20-4 methyl 2,3-dideoxy-6-O-p-toluenesulfonyl-β-D-erythro-hexopyranoside 
• 93105-96-5 4-O-benzyl-6-C-(n-butyl)-2,3,6-trideoxy-D-erythro-1,5-lactone 
• 137344-73-1 ((2R,3S,6R)-3-Benzyloxy-6-methoxy-tetrahydro-pyran-2-yl)-methanol 
• 92413-85-9 methyl-4-O-(t-butyldiphenylsilyl)-2,3-dideoxy-6-O-p-toluenesulfonyl-α-D-erythro-hexopyranoside 
• 93105-93-2 methyl-4-O-benzyl-6-C-(n-butylidene)-2,3,6-trideoxy-α-D-erythro-hexopyranoside 

Relevant articles and documents

Regio- And diastereoselective Pd-catalyzed synthesis of C2-aryl glycosides

An efficient regio- and diastereoselective arylation method of readily available 2,3-glycals with various aryl iodides has been established. Using the Pd(OAc)2/AsPh3 precatalytic system, this protocol proved to be general to prepare a variety of substituted C2-aryl glycosides in good yields with complete diastereoselectivity.

Montmorillonite-catalyzed glysosylation of alcohols with glycals derived from galactose and glucose under microwave-induced reactions

Montmorillonite K10-catalyzed glycosylation of alcohols with glycals obtained from galactose and glucose is performed efficiently using microwave irradiation with good anomeric selectivity.

Ruthenium Catalyzed Stereo/Chemo/Regioselective One-Pot Synthesis of C(2)-C(3) Unsaturated and α-d-Mannopyranosyl Sulfones

An efficient and divergent approach to C(2)-C(3) unsaturated glycosyl and α-d-mannopyranosyl sulfones has been developed via ruthenium-promoted direct glycosylation, oxidation, and dihydroxylation from glycal in one-pot. The presence of stoichiometric amounts of NaIO4 and in situ generation of RuO4 from a RuCl3-NaIO4 reagent system were crucial for chemoselective oxidation of sulfide in the presence of an olefin moiety. The dual-role of ruthenium in sequential glycosylation-oxidation-dihydroxylation is amenable to a wide range of thio acceptors to access α-d-mannopyranosyl sulfones in good yields with high regioselectivity.